Quantum spin liquid ground state in the rare-earth triangular antiferromagnet <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:msub><mml:mi>SmTa</mml:mi><mml:mn>7</mml:mn></mml:msub><mml:msub><mml:mi mathvariant="normal">O</mml

The rare-earth-based geometrically frustrated triangular magnets have attracted considerable attention due to the intricate interplay between strong spin-orbit coupling and the crystal electric field (CEF), which often leads to effective spin-1/2 degrees of freedom and therefore promotes strong quantum fluctuations at low temperatures, thus offering an excellent route to stabilize a quantum spin liquid (QSL) ground state. We have investigated the ground state magnetic properties of a polycrystalline sample of <a:math xmlns:a="http://www.w3.org/1998/Math/MathML"><a:mrow><a:msub><a:mtext>SmTa</a:mtext><a:mn>7</a:mn></a:msub><a:msub><a:mtext>O</a:mtext><a:mn>19</a:mn></a:msub></a:mrow></a:math> which we propose to have a gapless QSL ground state by employing powder x-ray diffraction (XRD), x-ray absorption spectroscopy (XAS), DC and AC-magnetic susceptibility, <b:math xmlns:b="http://www.w3.org/1998/Math/MathML"><b:mi>M</b:mi></b:math> versus <c:math xmlns:c="http://www.w3.org/1998/Math/MathML"><c:mi>H</c:mi></c:math> isotherm, specific heat, and muon spin rotation/relaxation measurements (<d:math xmlns:d="http://www.w3.org/1998/Math/MathML"><d:mrow><d:mo>µ</d:mo><d:mi>SR</d:mi></d:mrow></d:math>) down to 30 mK. The combined structural and electronic studies reveal the formation of an edge-sharing equilateral triangular lattice of <e:math xmlns:e="http://www.w3.org/1998/Math/MathML"><e:msup><e:mrow><e:mi>Sm</e:mi></e:mrow><e:mrow><e:mn>3</e:mn><e:mo>+</e:mo></e:mrow></e:msup></e:math> ions in <f:math xmlns:f="http://www.w3.org/1998/Math/MathML"><f:mrow><f:mi>a</f:mi><f:mi>b</f:mi></f:mrow></f:math> plane. The DC and AC magnetic susceptibility, and heat capacity measurements reveal that <g:math xmlns:g="http://www.w3.org/1998/Math/MathML"><g:mrow><g:msub><g:mtext>SmTa</g:mtext><g:mn>7</g:mn></g:msub><g:msub><g:mtext>O</g:mtext><g:mn>19</g:mn></g:msub></g:mrow></g:math> does not exhibit any long-range magnetic ordering transition down to 50 mK. The zero-field (ZF)-<h:math xmlns:h="http://www.w3.org/1998/Math/MathML"><h:mrow><h:mo>µ</h:mo><h:mi>SR</h:mi></h:mrow></h:math> study strongly refutes the long-range magnetically ordered ground state and/or any partial spin-freezing down to at least 30 mK. The ZF-muon-spin relaxation rate is weakly temperature-dependent between 50 and 20 K, rapidly increases below <i:math xmlns:i="http://www.w3.org/1998/Math/MathML"><i:mrow><i:mo>∼</i:mo><i:mn>20</i:mn><i:mspace width="4pt"/><i:mi mathvariant="normal">K</i:mi></i:mrow></i:math> and saturates at low temperatures between 2 K and 30 mK, which has been attributed to a characteristic signature of QSL systems. Further, our longitudinal-field (LF)-<l:math xmlns:l="http://www.w3.org/1998/Math/MathML"><l:mrow><l:mo>µ</l:mo><l:mi>SR</l:mi></l:mrow></l:math> measurements at 0.1 K reveal a dynamic nature of the magnetic ground state. In addition, our high-field specific heat data suggest a gapless nature of spin excitations in this compound.

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Journal
Physical review. B./Physical review. B
Published
2025-03-07
DOI
https://doi.org/10.1103/physrevb.111.104413
Citations
5
Primary Topic
Advanced Condensed Matter Physics
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article
Field-Weighted Citation Impact
6.29

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Quantum spin liquid ground state in the rare-earth triangular antiferromagnet <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:msub><mml:mi>SmTa</mml:mi><mml:mn>7</mml:mn></mml:msub><mml:msub><mml:mi mathvariant="normal">O</mml

Devashibhai Thakarshibhai Adroja, Dhanpal Bairwa, Hubertus Luetkens, T. J. Hicken et al.
5 citations
Physical review. B./Physical review. B
Advanced Condensed Matter Physics
6.29
article

Quantum spin liquid ground state in the rare-earth triangular antiferromagnet <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:msub><mml:mi>SmTa</mml:mi><mml:mn>7</mml:mn></mml:msub><mml:msub><mml:mi mathvariant="normal">O</mml

Devashibhai Thakarshibhai Adroja, Dhanpal Bairwa, Hubertus Luetkens, T. J. Hicken, Suja Elizabeth, A. Bandyopadhyay, Gavin B. G. Stenning, Sudhindra Rayaprol, Jonas A. Krieger, Giannantonio Cibin, P.D. Babu, M. Rotter
article en
5 citations

Abstract

The rare-earth-based geometrically frustrated triangular magnets have attracted considerable attention due to the intricate interplay between strong spin-orbit coupling and the crystal electric field (CEF), which often leads to effective spin-1/2 degrees of freedom and therefore promotes strong quantum fluctuations at low temperatures, thus offering an excellent route to stabilize a quantum spin liquid (QSL) ground state. We have investigated the ground state magnetic properties of a polycrystalline sample of <a:math xmlns:a="http://www.w3.org/1998/Math/MathML"><a:mrow><a:msub><a:mtext>SmTa</a:mtext><a:mn>7</a:mn></a:msub><a:msub><a:mtext>O</a:mtext><a:mn>19</a:mn></a:msub></a:mrow></a:math> which we propose to have a gapless QSL ground state by employing powder x-ray diffraction (XRD), x-ray absorption spectroscopy (XAS), DC and AC-magnetic susceptibility, <b:math xmlns:b="http://www.w3.org/1998/Math/MathML"><b:mi>M</b:mi></b:math> versus <c:math xmlns:c="http://www.w3.org/1998/Math/MathML"><c:mi>H</c:mi></c:math> isotherm, specific heat, and muon spin rotation/relaxation measurements (<d:math xmlns:d="http://www.w3.org/1998/Math/MathML"><d:mrow><d:mo>µ</d:mo><d:mi>SR</d:mi></d:mrow></d:math>) down to 30 mK. The combined structural and electronic studies reveal the formation of an edge-sharing equilateral triangular lattice of <e:math xmlns:e="http://www.w3.org/1998/Math/MathML"><e:msup><e:mrow><e:mi>Sm</e:mi></e:mrow><e:mrow><e:mn>3</e:mn><e:mo>+</e:mo></e:mrow></e:msup></e:math> ions in <f:math xmlns:f="http://www.w3.org/1998/Math/MathML"><f:mrow><f:mi>a</f:mi><f:mi>b</f:mi></f:mrow></f:math> plane. The DC and AC magnetic susceptibility, and heat capacity measurements reveal that <g:math xmlns:g="http://www.w3.org/1998/Math/MathML"><g:mrow><g:msub><g:mtext>SmTa</g:mtext><g:mn>7</g:mn></g:msub><g:msub><g:mtext>O</g:mtext><g:mn>19</g:mn></g:msub></g:mrow></g:math> does not exhibit any long-range magnetic ordering transition down to 50 mK. The zero-field (ZF)-<h:math xmlns:h="http://www.w3.org/1998/Math/MathML"><h:mrow><h:mo>µ</h:mo><h:mi>SR</h:mi></h:mrow></h:math> study strongly refutes the long-range magnetically ordered ground state and/or any partial spin-freezing down to at least 30 mK. The ZF-muon-spin relaxation rate is weakly temperature-dependent between 50 and 20 K, rapidly increases below <i:math xmlns:i="http://www.w3.org/1998/Math/MathML"><i:mrow><i:mo>∼</i:mo><i:mn>20</i:mn><i:mspace width="4pt"/><i:mi mathvariant="normal">K</i:mi></i:mrow></i:math> and saturates at low temperatures between 2 K and 30 mK, which has been attributed to a characteristic signature of QSL systems. Further, our longitudinal-field (LF)-<l:math xmlns:l="http://www.w3.org/1998/Math/MathML"><l:mrow><l:mo>µ</l:mo><l:mi>SR</l:mi></l:mrow></l:math> measurements at 0.1 K reveal a dynamic nature of the magnetic ground state. In addition, our high-field specific heat data suggest a gapless nature of spin excitations in this compound.

Physical review. B./Physical review. BVol. 111(10)
University of Johannesburg (ZA), Diamond Light Source (GB), UGC DAE Consortium for Scientific Research (IN), ISIS Neutron and Muon Source, Indian Institute of Science Bangalore (IN)
Engineering and Physical Sciences Research Council
Openalex Percentile: Top 4%
Advanced Condensed Matter Physics
6.29
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