Simple Manufacturing of Large Polypyrrole Free-Standing Films Made of Nanoplatelets

A simple method is developed to produce free-standing films of polypyrrole (PPy) in one step. It consists of the interfacial polymerization (without surfactants) of pyrrole (dissolved in chloroform) with an oxidant (ammonium persulfate, dissolved in water). It is observed that the area of the formed film only depends on the size of the interface, achieving the manufacture of PPy films of up to 300 cm2, with a thickness of 200 microns. Transmission electron microscopy (TEM) images show the presence of superimposed nanoplatelets of ca. 100 nm main axis. These nanoparticles seem to aggregate in two dimensions to form the free-standing film. Scanning electron microscopy (SEM) shows a compact surface with nanowires decorating the surface. PPy films show an electrical conductivity of 63 (±3) S cm−1. PPy conductive films are then applied in the construction of an antenna that shows a response in two bands: at 1.52 GHz (−13.85 dB) and at 3.50 GHz (−33.55 dB). The values are comparable to those of other antennas built with different PPy films. The simple synthesis of large-area PPy films in a single step would allow the fabrication of large quantities of electronic elements (e.g., sensors) with uniform properties in a short time.