Nature of the Order Parameters of Glass

In glass physics, order parameters have long been used in the thermodynamic description of glasses, but their nature is not yet clear. The difficulty is how to find order in disordered systems. This study provides a coherent understanding of the nature of order parameters for glasses and crystals, starting from the fundament of the definition of state variables in thermodynamics. The state variable is defined as the time-averaged value of a dynamical variable under the constraints, when equilibrium is established. It gives the same value at any time it is measured as long as the equilibrium is maintained. From this definition, it is deduced that the state variables of a solid are the time-averaged positions of all atoms constituting the solid, and the order parameters are essentially the same as state variables. Therefore, the order parameters of a glass are equilibrium atom positions.