Effects of Untreated Waste Lignin as a Sustainable Asphalt Emulsion Substitute on Water Resistance and Environmental Impacts in Reclaimed Half-Warm Asphalt Mixtures

Polymers are known to produce beneficial effects on asphalt mixtures, and lignin biopolymers could further improve them while contributing to sustainability and circularity. In this research, conventional asphalt emulsion was replaced with liquid waste containing lignin from the wood industry in half-warm mix asphalt (HWMA) at varying substitution levels of 0% (control), 5%, 10%, 15%, and 20%. Additionally, 100% reclaimed asphalt pavement (RAP) was used as aggregate. The impact of asphalt emulsion substitution on the mixtures’ adhesion, cohesion, and water resistance was analyzed. Indirect tensile strength tests evaluated the HWMA’s resistance to moisture damage and ductility. Rolling bottle and boiling water tests were conducted to assess the binder-aggregate affinity. Moreover, a Life Cycle Assessment (LCA) was performed to compare the environmental benefits of HWMA with those of Hot Mix Asphalt (HMA). The findings revealed that substituting asphalt emulsion with the waste lignin up to 15% enhances the mixture’s cohesion, while only substitutions up to 5% produce mixtures with enhanced water resistance. Environmental impacts were significantly reduced for all the HWMA studied, with the Global Warming Potential (GWP) showing up to 33.5% reduction compared to a conventional HMA.