Three Cases of Borates with Different Dimensional Frameworks Induced by Metal Cations
Three new metal borates containing d<sup>10</sup> cations, namely, Li<sub>4</sub>PbZn<sub>3</sub>B<sub>12</sub>O<sub>24</sub>, Na<sub>2</sub>Cd<sub>2</sub>B<sub>8</sub>O<sub>15,</sub> and K<sub>2</sub>Sr<sub>4</sub>ZnB<sub>10</sub>O<sub>19</sub>(CO<sub>3</sub>)<sub>2</sub>, were synthesized using the flux method. K<sub>2</sub>Sr<sub>4</sub>ZnB<sub>10</sub>O<sub>19</sub>(CO<sub>3</sub>)<sub>2</sub> is the first Zn-containing borate carbonate and has an unprecedented fundamental building block, [B<sub>10</sub>O<sub>22</sub>]. Furthermore, experimental and first-principles theoretical studies were performed.
Authors
- Fangfang Zhang (ORCID: https://orcid.org/0000-0002-8739-3446)
- Bingliang Cheng
- Zilong Chen (ORCID: https://orcid.org/0000-0003-4467-8537)
- Abudukadi Tudi (ORCID: https://orcid.org/0000-0002-3370-5205)
- Shilie Pan (ORCID: https://orcid.org/0000-0003-4521-4507)
- Xiaojing Li (ORCID: https://orcid.org/0000-0003-1660-3108)
- Zhihua Yang (ORCID: https://orcid.org/0000-0001-9214-3612)
Institutions
- Xinjiang Technical Institute of Physics & Chemistry (CN)
- University of Chinese Academy of Sciences (CN)
Publication Details
- Journal
- Inorganic Chemistry
- Published
- 2025-03-06
- DOI
- https://doi.org/10.1021/acs.inorgchem.5c00066
- Citations
- 1
- Primary Topic
- Crystal Structures and Properties
- Type
- article
- Field-Weighted Citation Impact
- 0.43
Funders
- National Natural Science Foundation of China
- Chinese Academy of Sciences
- National Key Research and Development Program of China