Improving the Compatibility of Epoxy Asphalt Based on Poly(styrene-butadiene-styrene)-Grafted Carbon Nanotubes

Epoxy asphalt, as a thermosetting and thermoplastic polymer composite material, has been widely used for steel bridge decks and specialty pavements due to its road performance, thermal stability, rutting resistance, and durability. However, the poor compatibility between epoxy resin binder and asphalt, due to the difference in chemical structure, polarity, and solubleness, severely restricts their practical applications in the construction of bridges and roads. Herein, we proposed a facial method to strengthen their compatibility by blending the poly(styrene-butadiene-styrene)-modified carbon nanotubes (SBS-CNTs) in the composite. The SBS-CNTs were found to evenly disperse in epoxy asphalt matrix with the epoxy resin contents of 10%–30% and could form the three-dimensional bi-continuous cross-linked structure at 30%. Moreover, the addition of epoxy resin increased the glass transition temperature (Tg) and enhanced the high-temperature shear capacity and tensile strength (over an order of magnitudes) of SBS-CNT-modified asphalt, which showed high potential for applications in the construction of bridges and roads, providing an alternative approach for improving the performance of epoxy asphalt.