Synthesis, crystal structure and Hirshfeld surface analysis of a propyl 4-{[1-(2-methyl-4-nitrophenyl)-1<i>H</i>-1,2,3-triazol-4-yl]methoxy}benzoate copper(II) chloride complex
The core of the title complex, di-chlorido-bis-(propyl 4-{[1-(2-methyl-4-nitro-phen-yl)-1<i>H</i>-1,2,3-triazol-4-yl]meth-oxy}benzoate)copper(II), [CuCl<sub>2</sub>(C<sub>20</sub>H<sub>20</sub>N<sub>4</sub>O<sub>5</sub>)<sub>2</sub>], which belongs to the copper(II) complex family, consists of two C<sub>20</sub>H<sub>20</sub>N<sub>4</sub>O<sub>5</sub> ligands and two chloride ligands arranged around the metal, forming a <i>trans</i>-di-chlorido square-planar complex. In the crystal, the mol-ecules are linked by C-H⋯Cl and C-H⋯O hydrogen bonds as well as by aromatic π-π stacking inter-actions into a three-dimensional network. To further analyse the inter-molecular inter-actions, a Hirshfeld surface analysis was performed.
Authors
- Akmaljon Tojiboev (ORCID: https://orcid.org/0000-0001-8061-0914)
- B. Tashkhodjaev (ORCID: https://orcid.org/0000-0003-3027-9893)
- Ilkhomjon Ortikov
- Muminjon Hakimov (ORCID: https://orcid.org/0009-0000-2805-4084)
- Tulkinjon Sattarov
Institutions
- Namangan State University (UZ)
- Yunusov Institute of the Chemistry of Plant Substances (UZ)
Publication Details
- Journal
- Acta Crystallographica Section E Crystallographic Communications
- Published
- 2025-03-04
- DOI
- https://doi.org/10.1107/s2056989025001732
- Citations
- 1
- Primary Topic
- Crystal structures of chemical compounds
- Type
- article
- Field-Weighted Citation Impact
- 0.54