Review of the Properties and Degradation Mechanisms of Refractories in Aluminum Reduction Cells

This review examines the degradation of refractory materials in aluminum reduction cells, focusing specifically on contamination caused by the cryolite-based bath. Aluminosilicate refractories, particularly Ordinary Refractory Bricks, play a vital role in maintaining the structural integrity and thermal balance of these cells under demanding operational conditions. The interaction between the molten bath and refractory linings leads to chemical reactions and mineralogical changes that modify the mechanical and thermal properties of the material over time. The study integrates findings from industrial autopsies, laboratory experiments, and a comprehensive review of the existing literature to identify and analyze the mechanisms of degradation. By analyzing the findings obtained from these methodologies, this review explores how cryolitic infiltration triggers transformations that compromise performance and reduce the lifespan of refractory linings. Covering a broad temperature range (665–960 °C), the study addresses key challenges in understanding bath-induced contamination and provides insights into how to improve the durability and efficiency of refractory materials in aluminum production.