Controllable p-Type Doping Strategy for High-Performance 2D Material Complementary Inverters

Controllable doping is required to modulate the electrical properties of the semiconductor devices. Such controllability is a particular issue in p-type doping for two-dimensional (2D) semiconductors. Here, we present a controllable doping strategy for modulating carrier density and threshold voltage of WSe<sub>2</sub> transistors via surface oxidation at 200 °C in air. The hole density in the WSe<sub>2</sub> channel can be precisely modulated from 1 × 10<sup>11</sup> cm<sup>-2</sup> to 3.5 × 10<sup>12</sup> cm<sup>-2</sup> by increasing oxidation duration, while its carrier mobility is virtually unaffected, maintaining a high value of 94.3 cm<sup>2</sup>·V<sup>-1</sup>·s<sup>-1</sup>. This controllable doping method can help to achieve balanced carrier transport in the n-type and p-type transistors in CMOS devices. The doped p-type WSe<sub>2</sub> transistor in a CMOS inverter resulted in a high gain of 52 and a lower static power of 0.256 nW at a bias voltage of 1 V. Therefore, our findings might pave the way for reliable fabrication of high-performance 2D electronic circuits.

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Publication Details

Journal
ACS Applied Materials & Interfaces
Published
2025-03-04
DOI
https://doi.org/10.1021/acsami.4c20474
Citations
5
Primary Topic
2D Materials and Applications
Type
article
Field-Weighted Citation Impact
2.59

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article

Controllable p-Type Doping Strategy for High-Performance 2D Material Complementary Inverters

Zhenda Xie, Juqing Liu, Zhong Yan, Jiawei Xue et al.
5 citations
ACS Applied Materials & Interfaces
2D Materials and Applications
2.59
article

Controllable p-Type Doping Strategy for High-Performance 2D Material Complementary Inverters

Zhenda Xie, Juqing Liu, Zhong Yan, Jiawei Xue, Yingchun Cheng, Hao Wu, Zheng Wu
article en
5 citations

Abstract

Controllable doping is required to modulate the electrical properties of the semiconductor devices. Such controllability is a particular issue in p-type doping for two-dimensional (2D) semiconductors. Here, we present a controllable doping strategy for modulating carrier density and threshold voltage of WSe<sub>2</sub> transistors via surface oxidation at 200 °C in air. The hole density in the WSe<sub>2</sub> channel can be precisely modulated from 1 × 10<sup>11</sup> cm<sup>-2</sup> to 3.5 × 10<sup>12</sup> cm<sup>-2</sup> by increasing oxidation duration, while its carrier mobility is virtually unaffected, maintaining a high value of 94.3 cm<sup>2</sup>·V<sup>-1</sup>·s<sup>-1</sup>. This controllable doping method can help to achieve balanced carrier transport in the n-type and p-type transistors in CMOS devices. The doped p-type WSe<sub>2</sub> transistor in a CMOS inverter resulted in a high gain of 52 and a lower static power of 0.256 nW at a bias voltage of 1 V. Therefore, our findings might pave the way for reliable fabrication of high-performance 2D electronic circuits.

ACS Applied Materials & InterfacesVol. 17(11)
Nanjing Tech University (CN), Nanjing University of Information Science and Technology (CN), Laboratoire de physique des Solides (FR), Yanshan University (CN), Beijing Institute of Optoelectronic Technology (CN), Collaborative Innovation Center of Advanced Microstructures (CN), Center for High Pressure Science and Technology Advanced Research (CN), State Key Laboratory of Metastable Materials Science and Technology, National Laboratory of Solid State Microstructures, Nanjing University (CN)
National Natural Science Foundation of China, China Postdoctoral Science Foundation, Natural Science Foundation of Jiangsu Province, Startup Foundation for Introducing Talent of Nanjing University of Information Science and Technology
Openalex Percentile: Top 11%
2D Materials and Applications
2.59
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