Adsorption of Lead (Pb(II)) from Contaminated Water onto Activated Carbon: Kinetics, Isotherms, Thermodynamics, and Modeling by Artificial Intelligence

Heavy metals, extensively used in various industrial applications, are among the most significant environmental pollutants due to their hazardous effects on human health and other living organisms. Removing these pollutants from the environment is essential. In this study, activated carbon (AC) (Carbon C) was employed to eliminate Pb(II) from water. The optimal removal conditions were determined as follows: a 50 mg dose of activated carbon, an initial Pb(II) concentration of 100 mg/L, pH 4, a temperature of 30 °C, and a contact time of 60 min Under these conditions, activated carbon achieved a Pb(II) removal efficiency of approximately 97.86%. The adsorption data for Pb(II) closely aligned with the 2nd-order kinetic model, and the equilibrium data were effectively described by the Langmuir isotherm equation. The maximum adsorption capacity of Pb(II), as determined by the Langmuir model, was 48.75 mg/g. These methods were successfully applied to remove Pb(II) from various environmental and industrial wastewater samples. To accurately predict the percentage of Pb(II) removal based on parameters such as pollutant type, carbon dosage, pH, initial concentration, temperature, and treatment duration, feed-forward neural networks (FFNNs) were utilized. The FFNN model demonstrated outstanding predictive accuracy, achieving a root mean square error (RMSE) of 0.03 and an R2 value of 0.996.