Grain-scale feedback between deformation mechanisms and metamorphic reactions: Dissolution-precipitation processes in the lower crust (Kågen gabbros)

• In kågen gabbros, strain is mainly accommodated by dissolution precipitation creep. • Homogenization of reactions is controlled at a scale of ∼100 µm. • Chemical equilibrium is reached locally, residual zoning reflects reaction progress. • Rheological laws should integrate dissolution-precipitation processes. Strain localization within crustal shear zones involves intricate feedback between deformation mechanisms, metamorphic reactions and fluid circulation. Despite evidence that these high-deformation zones proceed at least partly through dissolution-precipitation creep, available creep laws so far only account for dislocation creep and/or solid-state diffusion processes. Deciphering the role and the contribution of dissolution-precipitation creep to strain accommodation is now required to further understand the rheological behavior of polymineralic crustal rocks. This study combines high-resolution microstructural and compositional analytical techniques to track the progressive deformation of the Kågen metagabbros, at and below grain scale. The Kågen metagabbros preserved a strain and re-equilibration gradient over outcrop-scale, where metamorphic re-equilibrations and fluid infiltration took place at constant pressure and temperature representative of lower crustal conditions (ca. 1 GPa - 660 ± 25 °C). The comparison and quantification of chemical and microstructural information in this shear zone, through pixel-per-pixel and grain-per-grain correlated EPMA and EBSD maps, enables tracking grain-scale deformation mechanisms as well as the interplay between grain size reduction, mineral reactions, phase mixing and material transfer. Dissolution-precipitation creep appears dominant for strain accommodation in the Kågen metagabbros shear zone. As deformation progresses, nucleation of new metamorphic minerals (clinopyroxene, plagioclase, amphibole) allow for grain size reduction and compositional homogenization through dissolution, transport and precipitation processes associated with fluid ingression along grain boundaries. Intracrystalline plastic deformation is here insignificant for strain accommodation. Thermodynamic modeling and textural analysis reveal that re-equilibration processes are spatially controlled by microdomains where equilibrium is reached locally, on a scale of ∼100 µm. This study calls for integrating reactions, dissolution-precipitation processes, fluids and polymineralic assemblages into rheological laws for a reliable assessment of the mechanical evolution of metamorphic rocks.

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Publication Details

Journal
Earth and Planetary Science Letters
Published
2025-03-02
DOI
https://doi.org/10.1016/j.epsl.2025.119275
Citations
3
Primary Topic
Geological and Geochemical Analysis
Type
article
Field-Weighted Citation Impact
5.60

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article

Grain-scale feedback between deformation mechanisms and metamorphic reactions: Dissolution-precipitation processes in the lower crust (Kågen gabbros)

Jacques Précigout, Mathieu Soret, Holger Stünitz, Philippe Agard et al.
3 citations
Earth and Planetary Science Letters
Geological and Geochemical Analysis
5.60
article

Grain-scale feedback between deformation mechanisms and metamorphic reactions: Dissolution-precipitation processes in the lower crust (Kågen gabbros)

Jacques Précigout, Mathieu Soret, Holger Stünitz, Philippe Agard, Benoît Dubacq, Louise Mérit
article en
3 citations

Abstract

• In kågen gabbros, strain is mainly accommodated by dissolution precipitation creep. • Homogenization of reactions is controlled at a scale of ∼100 µm. • Chemical equilibrium is reached locally, residual zoning reflects reaction progress. • Rheological laws should integrate dissolution-precipitation processes. Strain localization within crustal shear zones involves intricate feedback between deformation mechanisms, metamorphic reactions and fluid circulation. Despite evidence that these high-deformation zones proceed at least partly through dissolution-precipitation creep, available creep laws so far only account for dislocation creep and/or solid-state diffusion processes. Deciphering the role and the contribution of dissolution-precipitation creep to strain accommodation is now required to further understand the rheological behavior of polymineralic crustal rocks. This study combines high-resolution microstructural and compositional analytical techniques to track the progressive deformation of the Kågen metagabbros, at and below grain scale. The Kågen metagabbros preserved a strain and re-equilibration gradient over outcrop-scale, where metamorphic re-equilibrations and fluid infiltration took place at constant pressure and temperature representative of lower crustal conditions (ca. 1 GPa - 660 ± 25 °C). The comparison and quantification of chemical and microstructural information in this shear zone, through pixel-per-pixel and grain-per-grain correlated EPMA and EBSD maps, enables tracking grain-scale deformation mechanisms as well as the interplay between grain size reduction, mineral reactions, phase mixing and material transfer. Dissolution-precipitation creep appears dominant for strain accommodation in the Kågen metagabbros shear zone. As deformation progresses, nucleation of new metamorphic minerals (clinopyroxene, plagioclase, amphibole) allow for grain size reduction and compositional homogenization through dissolution, transport and precipitation processes associated with fluid ingression along grain boundaries. Intracrystalline plastic deformation is here insignificant for strain accommodation. Thermodynamic modeling and textural analysis reveal that re-equilibration processes are spatially controlled by microdomains where equilibrium is reached locally, on a scale of ∼100 µm. This study calls for integrating reactions, dissolution-precipitation processes, fluids and polymineralic assemblages into rheological laws for a reliable assessment of the mechanical evolution of metamorphic rocks.

Earth and Planetary Science LettersVol. 656
Centre National de la Recherche Scientifique (FR), Institut Universitaire de France (FR), China University of Geosciences (CN), Sorbonne Université (FR), Institut des Sciences de la Terre de Paris (FR), Institut des Sciences de la Terre (FR), Bureau de Recherches Géologiques et Minières (FR), Laboratoire de Géologie de l’École Normale Supérieure (FR)
Institut Universitaire de France, European Research Council
Climate action
Openalex Percentile: Top 5%
Geological and Geochemical Analysis
5.60
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