Epi-grown broadband reflector for InAs-based thermophotovoltaics

Reflecting sub-bandgap photons is crucial for maximizing the efficiency of thermophotovoltaic devices. However, existing metal-deposited reflectors rely on back-side metallization, which cannot be grown epitaxially, necessitating additional processing steps. In this study, we fabricate InAs-based thermophotovoltaic devices featuring a straightforward, epitaxially grown sub-bandgap reflector composed of a single layer of n-doped InAs at a doping concentration of 2.4 × 10 19 cm −3 . This high doping produces long-wavelength metallic-like reflection, and our devices demonstrate high sub-bandgap reflectivity from 3.5 to 17 μm, achieving up to 93 % reflectivity compared to 30–40 % for designs without the reflector. Using a calibrated optical model, we predict that the sub-bandgap reflectivity of this layer enhances spectral efficiency from 38 % to 79 % under a 600 K normally incident blackbody spectrum. This improvement rivals that of a standard gold back reflector, which achieves a spectral efficiency of 94 %. Additionally, our predictive electrical model, calibrated with fabricated devices, indicates that the reflective layer does not adversely affect the electrical properties of the thermophotovoltaic devices. This sub-bandgap reflector can be integrated into existing InAs-based thermophotovoltaic fabrication processes, eliminating complex substrate removal steps required for traditional gold reflectors. • Demonstrated sub-bandgap reflectivity of up to 93 % for devices with a n-InAs reflective layer. • The reflective layer can improve spectral efficiency from 38 % to 79 %, under a 600 K normally incident blackbody spectrum. • Measurement and simulation results reveal that the reflective layer does not adversely affect the electrical properties of the devices.

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Publication Details

Journal
Solar Energy Materials and Solar Cells
Published
2025-03-01
DOI
https://doi.org/10.1016/j.solmat.2025.113544
Citations
2
Primary Topic
Thermal Radiation and Cooling Technologies
Type
article
Field-Weighted Citation Impact
1.91
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article

Epi-grown broadband reflector for InAs-based thermophotovoltaics

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2 citations
Solar Energy Materials and Solar Cells
Thermal Radiation and Cooling Technologies
1.91
article

Epi-grown broadband reflector for InAs-based thermophotovoltaics

Man Chun Tam, Karin Hinzer, Z. R. Wasilewski, Jacob J. Krich, Gavin P. Forcade, Raphaël St-Gelais, Mathieu de Lafontaine, Mathieu Giroux
article en
2 citations

Abstract

Reflecting sub-bandgap photons is crucial for maximizing the efficiency of thermophotovoltaic devices. However, existing metal-deposited reflectors rely on back-side metallization, which cannot be grown epitaxially, necessitating additional processing steps. In this study, we fabricate InAs-based thermophotovoltaic devices featuring a straightforward, epitaxially grown sub-bandgap reflector composed of a single layer of n-doped InAs at a doping concentration of 2.4 × 10 19 cm −3 . This high doping produces long-wavelength metallic-like reflection, and our devices demonstrate high sub-bandgap reflectivity from 3.5 to 17 μm, achieving up to 93 % reflectivity compared to 30–40 % for designs without the reflector. Using a calibrated optical model, we predict that the sub-bandgap reflectivity of this layer enhances spectral efficiency from 38 % to 79 % under a 600 K normally incident blackbody spectrum. This improvement rivals that of a standard gold back reflector, which achieves a spectral efficiency of 94 %. Additionally, our predictive electrical model, calibrated with fabricated devices, indicates that the reflective layer does not adversely affect the electrical properties of the thermophotovoltaic devices. This sub-bandgap reflector can be integrated into existing InAs-based thermophotovoltaic fabrication processes, eliminating complex substrate removal steps required for traditional gold reflectors. • Demonstrated sub-bandgap reflectivity of up to 93 % for devices with a n-InAs reflective layer. • The reflective layer can improve spectral efficiency from 38 % to 79 %, under a 600 K normally incident blackbody spectrum. • Measurement and simulation results reveal that the reflective layer does not adversely affect the electrical properties of the devices.

Solar Energy Materials and Solar CellsVol. 285
University of Waterloo (CA), University of Ottawa (CA)
Affordable and clean energy
Openalex Percentile: Top 17%
Thermal Radiation and Cooling Technologies
1.91
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