Statistical and kinematic arrangements and their thermodynamic and informational interpretations: Gibbs paradox

Abstract A new way to deal with the given topic is the approach of finding the connection between the mathematical definitions of statistical and information entropy, as well as their mutual relations within the system of stochastic quantities. Especially with thermodynamic entropies expressed on an isolated system in which our repeatable observations are made and where it is a cyclic conversion of thermal energy within the observed/measured system. At the same time, we use the description of information to analyze the Gibbs paradox, which is also a current property of such observation/measurement of an equilibrium thermodynamic system. Although not immediately obvious in the first connection with the thermal analysis, it indicates a whole series of questions not yet solved but greedy like this one.

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Publication Details

Journal
Journal of Thermal Analysis and Calorimetry
Published
2025-03-01
DOI
https://doi.org/10.1007/s10973-025-14005-1
Primary Topic
Advanced Thermodynamics and Statistical Mechanics
Type
article
Field-Weighted Citation Impact
0.00

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article

Statistical and kinematic arrangements and their thermodynamic and informational interpretations: Gibbs paradox

Jaroslav Šesták, Bohdan Hejna
1 links
Journal of Thermal Analysis and Calorimetry
Advanced Thermodynamics and Statistical Mechanics
article

Statistical and kinematic arrangements and their thermodynamic and informational interpretations: Gibbs paradox

Jaroslav Šesták, Bohdan Hejna
article en

Abstract

Abstract A new way to deal with the given topic is the approach of finding the connection between the mathematical definitions of statistical and information entropy, as well as their mutual relations within the system of stochastic quantities. Especially with thermodynamic entropies expressed on an isolated system in which our repeatable observations are made and where it is a cyclic conversion of thermal energy within the observed/measured system. At the same time, we use the description of information to analyze the Gibbs paradox, which is also a current property of such observation/measurement of an equilibrium thermodynamic system. Although not immediately obvious in the first connection with the thermal analysis, it indicates a whole series of questions not yet solved but greedy like this one.

Journal of Thermal Analysis and CalorimetryVol. 150(7)
Czech Technical University in Prague (CZ), University of Chemistry and Technology, Prague (CZ), University of West Bohemia in Pilsen (CZ)
Vysoká Škola Chemicko-technologická v Praze
Openalex Percentile: Top 97%
Advanced Thermodynamics and Statistical Mechanics
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Statistical and kinematic arrangements and their thermodynamic and informational interpretations: Gibbs paradox — Jaroslav Šesták, Bohdan Hejna · Journal of Thermal Analysis and Calorimetry (2025) | TGRS Research Map | TGRS