Chemical potential and variable number of particles control the quantum state: Quantum oscillators as a showcase

Despite their simplicity, quantum harmonic oscillators are ubiquitous in the modeling of physical systems. They are able to capture universal properties that serve as references for the more complex systems found in nature. In this spirit, we apply a model of a Hamiltonian for open quantum systems in equilibrium with a particle reservoir to ensembles of quantum oscillators. By treating (i) a dilute gas of vibrating particles and (ii) a chain of coupled oscillators as showcases, we demonstrate that the property of varying numbers of particles leads to a mandatory condition on the energy of the system. In particular, the chemical potential plays the role of a parameter of control that can externally manipulate the spectrum of a system and the corresponding accessible quantum states.

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Publication Details

Journal
APL Quantum
Published
2025-02-28
DOI
https://doi.org/10.1063/5.0251102
Citations
2
Primary Topic
Spectroscopy and Quantum Chemical Studies
Type
article
Field-Weighted Citation Impact
2.49

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article

Chemical potential and variable number of particles control the quantum state: Quantum oscillators as a showcase

Luigi Delle Site, Ana Djurdjevac, Benedikt M. Reible
2 citations
APL Quantum
Spectroscopy and Quantum Chemical Studies
2.49
article

Chemical potential and variable number of particles control the quantum state: Quantum oscillators as a showcase

Luigi Delle Site, Ana Djurdjevac, Benedikt M. Reible
article en
2 citations

Abstract

Despite their simplicity, quantum harmonic oscillators are ubiquitous in the modeling of physical systems. They are able to capture universal properties that serve as references for the more complex systems found in nature. In this spirit, we apply a model of a Hamiltonian for open quantum systems in equilibrium with a particle reservoir to ensembles of quantum oscillators. By treating (i) a dilute gas of vibrating particles and (ii) a chain of coupled oscillators as showcases, we demonstrate that the property of varying numbers of particles leads to a mandatory condition on the energy of the system. In particular, the chemical potential plays the role of a parameter of control that can externally manipulate the spectrum of a system and the corresponding accessible quantum states.

APL QuantumVol. 2(1)
Institute of Mathematics and Informatics (BG), Czech Academy of Sciences, Institute of Mathematics (CZ), Freie Universität Berlin (DE)
Deutsche Forschungsgemeinschaft
Openalex Percentile: Top 13%
Spectroscopy and Quantum Chemical Studies
2.49
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Chemical potential and variable number of particles control the quantum state: Quantum oscillators as a showcase — Luigi Delle Site, Ana Djurdjevac, et al. · APL Quantum (2025) | TGRS Research Map | TGRS