Electron Attachment to Nitric Oxide (NO) Controversy

We report novel total electron scattering cross sections (TCS) from nitric oxide (NO) in the impact energy range from 1 to 15 eV by using a magnetically confined electron transmission apparatus. The accuracy of the data to within 5% and its consistency across the energy range investigated, shows significant discrepancies from previous works as to the major resonance features and magnitude of the TCS. Within the shape of the TCS, we have identified nine features which have been assigned to electron attachment resonances, most of them reported for the first time, while a comprehensive analysis of those peaking at 7.0, 7.8, and 8.8 eV has led to solve the controversy about dissociative electron attachment (DEA) cross-section that persisted for more than 50 years.

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Publication Details

Journal
The Journal of Physical Chemistry A
Published
2025-02-28
DOI
https://doi.org/10.1021/acs.jpca.4c07675
Citations
1
Primary Topic
Catalytic Processes in Materials Science
Type
article
Field-Weighted Citation Impact
0.52

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article

Electron Attachment to Nitric Oxide (NO) Controversy

A. Lozano, J. C. Oller, P. Limão-Vieira, G. Garcı́a
1 citations
The Journal of Physical Chemistry A
Catalytic Processes in Materials Science
0.52
article

Electron Attachment to Nitric Oxide (NO) Controversy

A. Lozano, J. C. Oller, P. Limão-Vieira, G. Garcı́a
article en
1 citations

Abstract

We report novel total electron scattering cross sections (TCS) from nitric oxide (NO) in the impact energy range from 1 to 15 eV by using a magnetically confined electron transmission apparatus. The accuracy of the data to within 5% and its consistency across the energy range investigated, shows significant discrepancies from previous works as to the major resonance features and magnitude of the TCS. Within the shape of the TCS, we have identified nine features which have been assigned to electron attachment resonances, most of them reported for the first time, while a comprehensive analysis of those peaking at 7.0, 7.8, and 8.8 eV has led to solve the controversy about dissociative electron attachment (DEA) cross-section that persisted for more than 50 years.

The Journal of Physical Chemistry AVol. 129(10)
Consejo Superior de Investigaciones Científicas (ES), Instituto de Física Fundamental (ES), Centro de Investigaciones Energéticas, Medioambientales y Tecnológicas (ES), Universidade Nova de Lisboa (PT)
European Association of National Metrology Institutes, Ministerio de Ciencia, Innovación y Universidades, Ministerio de Ciencia e Innovación
Openalex Percentile: Top 41%
Catalytic Processes in Materials Science
0.52
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