Influence of La/Al Doping via Magnetron Sputtering on the Mechanical and Tribological Properties of TiN Coatings

Adding alloying elements to binary nitrides enables the design of hard and tough coatings. To improve the mechanical and tribological performances of TiN-based coatings, La atoms were added to TiAlN coatings to form TiAlLaN coatings. Magnetron sputtering was conducted to prepare the TiAlLaN coatings. Thereafter, scanning electron microscopy (SEM), x-ray diffraction (XRD), nano-indentation, and a tribometer were utilized to test their microstructure, phases, and mechanical and tribological performances. Next, this study analyzed how lanthanum affected the microstructure and tribological performances of the TiAlLaN coatings. Incorporating La atoms in TiAlN coatings reduced the crystallite size and enhanced the coating toughness and hardness. The hardness H and elastic modulus E of the TiAlLaN coatings first increased and then decreased with the increase in La. Meanwhile, the coatings had improved wear and friction properties. The increased H/E and H3/E2 levels, which have been considered to reflect the hard coating’s toughness, were acquired based on the TiAlLaN coating, possessing enhanced hardness (19.8 GPa). The coefficient of friction and the wear rates of the coatings reduced and then increased with the increase in La. The TiAlLaN coating with 1.4 % of lanthanum had the lowest friction coefficient and wear rate of around 0.383 and 1.59 × 10−8 mm3/N·m, respectively, corresponding to a higher H/E (~0.086) and H3/E2 (~0.147 GPa). Adding an appropriate amount of La can substantially enhance the TiAlN coating’s tribological and mechanical properties. The TiAlLaN coating with remarkable characteristics may be applied to a steel substrate.