Oxidative Stability of Sunflower Oil: Effect of Blending with an Oil Extracted from Myrtle Liqueur By-Product

Myrtle oil extracted from the spent berries of myrtle liqueur production, using 2-methyltetrahydrofuran, was used to increase the oxidative stability of sunflower oil (SFO). Three blending ratios (5%, 10%, and 15% <i>w</i>/<i>w</i>) and the SFO without any addition were subjected to forced aging conditions at 70 °C for 21 days. The changes in peroxide value (PV), p-anisidine value (AV), total oxidation value (totox), and conjugated dienes and trienes were evaluated during forced aging. The oxidative stability of the blends was also assessed by the spin trapping method coupled with Electron Paramagnetic Resonance spectroscopy. Myrtle oil at 5% provided the best results, increasing the oxidative stability of SFO by reducing the PV and slowing the onset of secondary oxidation products, as measured by the AV and conjugated trienes. The 15% blend, despite its high levels of PV, AV, conjugated dienes, and trienes during storage, protects SFO from oxidation. The blends of SFO with unconventional oils, like myrtle oil, could represent a sustainable approach to increase its oxidative stability during storage.