Photo‐Induced Cracking in a Bi‐Component Molecular Solid: Capturing Structural Intermediates

A photo-responsive bi-component solid is designed based on robust large synthons. The study not only provides a template-based approach for a system that was difficult to photo-dimerize, but the designed solid also leads to photo-induced cracking upon photodimerization. The delicate structural design helps in capturing the structural intermediates, which reveals a possible reorientation of the photodimer within the crystal to maintain structural integrity.

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Publication Details

Journal
Chemistry - An Asian Journal
Published
2025-02-26
DOI
https://doi.org/10.1002/asia.202401518
Citations
3
Primary Topic
Crystallography and molecular interactions
Type
article
Field-Weighted Citation Impact
5.26

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article

Photo‐Induced Cracking in a Bi‐Component Molecular Solid: Capturing Structural Intermediates

Mollah Rohan Ahsan, Manish Kumar Mishra, Arijit Mukherjee
3 citations
Chemistry - An Asian Journal
Crystallography and molecular interactions
5.26
article

Photo‐Induced Cracking in a Bi‐Component Molecular Solid: Capturing Structural Intermediates

Mollah Rohan Ahsan, Manish Kumar Mishra, Arijit Mukherjee
article en
3 citations

Abstract

A photo-responsive bi-component solid is designed based on robust large synthons. The study not only provides a template-based approach for a system that was difficult to photo-dimerize, but the designed solid also leads to photo-induced cracking upon photodimerization. The delicate structural design helps in capturing the structural intermediates, which reveals a possible reorientation of the photodimer within the crystal to maintain structural integrity.

Chemistry - An Asian JournalVol. 20(9)
National Chemical Laboratory (IN), Birla Institute of Technology and Science - Hyderabad Campus (IN), Academy of Scientific and Innovative Research (IN)
Birla Institute of Technology and Science, Pilani, Science and Engineering Research Board
Openalex Percentile: Top 6%
Crystallography and molecular interactions
5.26
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