Shock‐heated graphite in three <scp>IAB</scp> iron meteorites—Implications on the formation of diamond

Abstract Iron meteorites, originating from the deepest parts of their parent bodies and separated during major break‐up events, surprisingly rarely contain diamonds despite experiencing similar pressure–temperature conditions as diamond‐bearing ureilites. In this study, graphite from three non‐magmatic IAB iron meteorites Canyon Diablo, Campo del Cielo, and Yardymly was analyzed using micro‐Raman spectroscopy, revealing the presence of the graphite G‐band, the disorder‐induced D‐band, and occasionally the D′‐band. Temperature estimates based on the G‐band full width at half maximum (ranging from 1155 to 1339°C) are consistent with those found in ureilites. However, unlike in ureilites, no diamond bands were detected, as confirmed by μ‐X‐ray diffraction. The absence of diamonds is interpreted to be related to the thermal and mechanical properties of the iron meteorite matrix. Its high thermal diffusivity results in similar temperatures to ureilites, but its ductility dissipates shock‐wave energy through plastic deformation, unlike the brittle ureilite matrix, which more effectively transmits the energy. Consequently, graphite in iron meteorites was heated but did not experience the high‐pressure conditions required for diamond formation. Thus, we propose that impacts must either involve substantial energy or that graphite must be located close to the impact site, where it can experience high energies before these dissipate.

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Publication Details

Journal
Meteoritics and Planetary Science
Published
2025-02-23
DOI
https://doi.org/10.1111/maps.14326
Citations
3
Primary Topic
Astro and Planetary Science
Type
article
Field-Weighted Citation Impact
3.46

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article

Shock‐heated graphite in three IAB iron meteorites—Implications on the formation of diamond

Matteo Alvaro, Fabrizio Nestola, Anna Barbaro, L. Ferrière et al.
3 citations
Meteoritics and Planetary Science
Astro and Planetary Science
3.46
article

Shock‐heated graphite in three IAB iron meteorites—Implications on the formation of diamond

Matteo Alvaro, Fabrizio Nestola, Anna Barbaro, L. Ferrière, Lidia Pittarello, Oliver Christ, M. C. Domeneghetti, Frank E. Brenker
article en
3 citations

Abstract

Abstract Iron meteorites, originating from the deepest parts of their parent bodies and separated during major break‐up events, surprisingly rarely contain diamonds despite experiencing similar pressure–temperature conditions as diamond‐bearing ureilites. In this study, graphite from three non‐magmatic IAB iron meteorites Canyon Diablo, Campo del Cielo, and Yardymly was analyzed using micro‐Raman spectroscopy, revealing the presence of the graphite G‐band, the disorder‐induced D‐band, and occasionally the D′‐band. Temperature estimates based on the G‐band full width at half maximum (ranging from 1155 to 1339°C) are consistent with those found in ureilites. However, unlike in ureilites, no diamond bands were detected, as confirmed by μ‐X‐ray diffraction. The absence of diamonds is interpreted to be related to the thermal and mechanical properties of the iron meteorite matrix. Its high thermal diffusivity results in similar temperatures to ureilites, but its ductility dissipates shock‐wave energy through plastic deformation, unlike the brittle ureilite matrix, which more effectively transmits the energy. Consequently, graphite in iron meteorites was heated but did not experience the high‐pressure conditions required for diamond formation. Thus, we propose that impacts must either involve substantial energy or that graphite must be located close to the impact site, where it can experience high energies before these dissipate.

Meteoritics and Planetary ScienceVol. 60(4)
Goethe University Frankfurt (DE), Natural History Museum Vienna (AT), University of Padua (IT), University of Pavia (IT), Emirates Foundation (AE)
Agenzia Spaziale Italiana
Openalex Percentile: Top 9%
Astro and Planetary Science
3.46
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