Impedance spectroscopy of hollandite-like ceramic composite material of K2O-MnO-Cr2O3-TiO2 system

The electrochemical properties of a ceramic composite material in which a hollandite-like potassiumchromium titanate solid solution is presented as the main phase were studied using impedance spectroscopy. The dependences of the conductivity of the obtained composites on temperature in the range from 250 to 800°C were studied. The activation energies of volumetric, intergranular and grain volume conductivity were determined. The phase composition of the material and the crystallographic structures of individual phases were also established.

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Publication Details

Journal
Electrochemical Energetics
Published
2025-02-21
DOI
https://doi.org/10.18500/1608-4039-2025-25-1-33-44
Primary Topic
Pigment Synthesis and Properties
Type
article
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article

Impedance spectroscopy of hollandite-like ceramic composite material of K2O-MnO-Cr2O3-TiO2 system

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Electrochemical Energetics
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Impedance spectroscopy of hollandite-like ceramic composite material of K2O-MnO-Cr2O3-TiO2 system

В. Г. Гоффман, Alexey M. Bainyashev, E. V. Tret’yachenko, María Vikulova, Alexander V. Gorokhovsky, A. D. Makarov, Valerii А. Rzaev
article en

Abstract

The electrochemical properties of a ceramic composite material in which a hollandite-like potassiumchromium titanate solid solution is presented as the main phase were studied using impedance spectroscopy. The dependences of the conductivity of the obtained composites on temperature in the range from 250 to 800°C were studied. The activation energies of volumetric, intergranular and grain volume conductivity were determined. The phase composition of the material and the crystallographic structures of individual phases were also established.

Electrochemical EnergeticsVol. 25(1)
Openalex Percentile: Top 97%
Pigment Synthesis and Properties
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