The statistical ensemble of q-deformed hyperbolic modified P\"oschl-Teller potential for certain diatomic molecules through Euler-Maclaurin  approach

The statistical properties are essentially needed to understand the macroscopic behaviours of atomic molecules, which is a crucial aspect of physics and chemistry research. In this work, q-deformed hyperbolic modified P"oschl-teller was used to obtain the statistical properties of $\mathrm{H_{2}}$, $\mathrm{HCl}$, $\mathrm{LiH}$, and $\mathrm{CO}$ using the energy eigenvalues that were gotten from the potential. The Nikiforov-Uvarov approach was used to elucidate the Schr"odinger equation using the potential, while the partition functions were obtained through the Euler-MacLaurin technique. The result shows that both the partition functions and each of the statistical properties increase with an increase in the Boltzmann factor. The analytical results of vibrational internal energy, vibrational entropy, vibrational free energy, and vibrational specific heat capacity were obtained for the limit $0<q\leq 1$. The study comes up with a new way to predict how potential deformation will affect the thermodynamic properties of diatomic molecules and the existence critical temperature which explain the phase transition of the diatomic particles. It also gives us useful information about the statistical properties of diatomic molecules, which helps us understand how they behave at the macro level. This is a big step forward for molecular physics.

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Publication Details

Journal
Journal of the Nigerian Society of Physical Sciences
Published
2025-02-26
DOI
https://doi.org/10.46481/jnsps.2025.2352
Citations
1
Primary Topic
Statistical Mechanics and Entropy
Type
article
Field-Weighted Citation Impact
1.32
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article

The statistical ensemble of q-deformed hyperbolic modified P\"oschl-Teller potential for certain diatomic molecules through Euler-Maclaurin  approach

K. J. Oyewumi, Olamide Olusesi, W. A. Yahya
1 citations
Journal of the Nigerian Society of Physical Sciences
Statistical Mechanics and Entropy
1.32
article

The statistical ensemble of q-deformed hyperbolic modified P\"oschl-Teller potential for certain diatomic molecules through Euler-Maclaurin  approach

K. J. Oyewumi, Olamide Olusesi, W. A. Yahya
article en
1 citations

Abstract

The statistical properties are essentially needed to understand the macroscopic behaviours of atomic molecules, which is a crucial aspect of physics and chemistry research. In this work, q-deformed hyperbolic modified P\"oschl-teller was used to obtain the statistical properties of $\mathrm{H_{2}}$, $\mathrm{HCl}$, $\mathrm{LiH}$, and $\mathrm{CO}$ using the energy eigenvalues that were gotten from the potential. The Nikiforov-Uvarov approach was used to elucidate the Schr\"odinger equation using the potential, while the partition functions were obtained through the Euler-MacLaurin technique. The result shows that both the partition functions and each of the statistical properties increase with an increase in the Boltzmann factor. The analytical results of vibrational internal energy, vibrational entropy, vibrational free energy, and vibrational specific heat capacity were obtained for the limit $0<q\leq 1$. The study comes up with a new way to predict how potential deformation will affect the thermodynamic properties of diatomic molecules and the existence critical temperature which explain the phase transition of the diatomic particles. It also gives us useful information about the statistical properties of diatomic molecules, which helps us understand how they behave at the macro level. This is a big step forward for molecular physics.

Journal of the Nigerian Society of Physical Sciences
University of Ilorin (NG), Kwara State University (NG)
Openalex Percentile: Top 22%
Statistical Mechanics and Entropy
1.32
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