Industrially Promising Catalytic Processes Involving Molybdovanadophosphoric Heteropoly Acid Solutions

The review discusses the most significant catalytic processes involving solutions of Mo–V–P heteropoly acids (HPA-x, where x is the number of V atoms), which have been developed at Boreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences. The prospects for using modified HPA-x solutions as oxidation and bifunctional catalysts are shown. The unique thermal stability and oxidation capacity of these systems make it possible to approach the implementation of optimum routes to synthesizing substances exhibiting activity in delignification, the development of highly selective key stages of the synthesis of vitamins K and E, and the neutralization of highly toxic gases (CO) without their predrying.

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Publication Details

Journal
Kinetics and Catalysis
Published
2024-12-01
DOI
https://doi.org/10.1134/s0023158424602377
Primary Topic
Polyoxometalates: Synthesis and Applications
Type
article
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article

Industrially Promising Catalytic Processes Involving Molybdovanadophosphoric Heteropoly Acid Solutions

Yu. A. Rodikova, Е. Г. Жижина
1 links
Kinetics and Catalysis
Polyoxometalates: Synthesis and Applications
article

Industrially Promising Catalytic Processes Involving Molybdovanadophosphoric Heteropoly Acid Solutions

Yu. A. Rodikova, Е. Г. Жижина
article en

Abstract

The review discusses the most significant catalytic processes involving solutions of Mo–V–P heteropoly acids (HPA-x, where x is the number of V atoms), which have been developed at Boreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences. The prospects for using modified HPA-x solutions as oxidation and bifunctional catalysts are shown. The unique thermal stability and oxidation capacity of these systems make it possible to approach the implementation of optimum routes to synthesizing substances exhibiting activity in delignification, the development of highly selective key stages of the synthesis of vitamins K and E, and the neutralization of highly toxic gases (CO) without their predrying.

Kinetics and CatalysisVol. 65(6)
Boreskov Institute of Catalysis (RU)
Openalex Percentile: Top 83%
Polyoxometalates: Synthesis and Applications
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