Fluorescent carbon quantum dots from Syzygium aromaticum as a selective sensor for Fe3+ and Cd2+ detection in aqueous solution
Fluorescent carbon quantum dots (SA-CQDs) from Syzygium aromaticum were synthesized via carbonization-assisted ultrasonication, exhibiting an average size of 3.314 nm and strong blue fluorescence at 440 nm (excitation: 350 nm) with a quantum yield of 12.61 %. FTIR and UV–vis confirmed oxygen-containing functional groups, enhancing metal ion interactions. SA-CQDs showed selective fluorescence quenching for Fe 3+ (89.7 %) and Cd 2+ (84.8 %). Sensitivity analysis revealed linearity (R 2 = 0.988 for Fe 3+ , R 2 = 0.994 for Cd 2+ ) with detection limits of 0.515 μM and 0.403 μM, respectively. High recovery rates (95.10–100.23 %) in real water samples confirmed reliability for water quality monitoring. • SA-CQDs selectively detect Fe 3+ and Cd 2+ with strong fluorescence quenching. • High sensitivity with low detection limits of 0.515 μM (Fe 3+ ) and 0.403 μM (Cd 2+ ). • Stable fluorescence in real water samples with high recovery and low RSD values. • Cost-effective sensor for heavy metal detection in aqueous environments.
Authors
- Ilham Zulfahmi (ORCID: https://orcid.org/0000-0001-9997-9068)
- Zulkarnain Jalil
- Edy Miswar
- Said Ali Akbar (ORCID: https://orcid.org/0000-0003-3678-1921)
- Muhammad Iqhrammullah (ORCID: https://orcid.org/0000-0001-8060-7088)
- Muhammad Nazar (ORCID: https://orcid.org/0000-0001-8361-606X)
- Muhammad Hasan (ORCID: https://orcid.org/0000-0003-2494-0796)
Institutions
- Universitas Syiah Kuala (ID)
- Universitas Muhammadiyah Aceh (ID)
Publication Details
- Journal
- Case Studies in Chemical and Environmental Engineering
- Published
- 2025-02-24
- DOI
- https://doi.org/10.1016/j.cscee.2025.101166
- Citations
- 6
- Primary Topic
- Carbon and Quantum Dots Applications
- Type
- article
- Field-Weighted Citation Impact
- 3.11