Investigation of Pore Size Effect on the Infiltration Process of Ti6Al4V/xAg Metal Matrix Composites

This work investigates the fabrication of Ti6Al4V composites manufactured by powder metallurgy through pressureless infiltration. Porous Ti6Al4V alloy compacts with different particle sizes were fabricated by sintering and then, liquid Ag was infiltrated to obtain composites. Computed microtomography was used to analyze the samples before and after infiltration. Numerical flow simulations and dilatometry tests evaluated the kinetics of Ag infiltration into porous Ti6Al4V compacts. Microstructure was observed by SEM and mechanical strength was evaluated by compression tests. Results showed that the pore properties play a crucial role in the infiltration timing and the distribution of the Ag's liquid. In particular, large pores allowed the infiltration to start a few °C degrees earlier than samples with smaller pores. Three-dimensional images after infiltration showed that most of the pores were filled and the remaining ones were isolated. The resulting microstructure was composed of Ti₂Ag, α-Ti and Ag phases, indicating that the Ag diffusion occurred. Furthermore, the mechanical strength depends on the interparticle neck sizes and the Ag improves the plastic deformation reached during compression tests. The best results were obtained for the samples with larger pore sizes because the resulting mechanical properties (E = 23 GPa and σ_y = 403 MPa) are close to that of human bones, making it the best candidate as an antibacterial material for biomedical use.