A Model of a “Smart” Thermoresponsive Composite with Convertible Surface Geometry Controlled by the Magnetocaloric Effect

A model of a “smart” composite based on a thermosensitive PNIPAM polymer deposited on a FeRh substrate with a modified periodic microstructure was proposed. The initial parameters of the model were determined from the properties of the actual composite sample and its components. Cooling of the sample using a magnetic field was shown by two independent methods, and at ~37 °C, it was −5.5 °C when a magnetic field of 1.8 T was applied. Based on experimental data, models of traditional and modified PNIPAM/FeRh composites were constructed. Calculations show that surface modification allows for an increase in the activation time for a polymer layer that is 20 µm thick from ~20 ms for a conventional composite to ~60 ms for a modified composite. Modification of the surface in the form of wells can be used to more effectively implement the idea of loading and releasing drugs for potential biomedical applications.

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Publication Details

Journal
Journal of Composites Science
Published
2025-02-21
DOI
https://doi.org/10.3390/jcs9030097
Primary Topic
Advanced Materials and Mechanics
Type
article
Field-Weighted Citation Impact
0.00

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article

A Model of a “Smart” Thermoresponsive Composite with Convertible Surface Geometry Controlled by the Magnetocaloric Effect

E. K. Murliev, А. П. Каманцев, I. М. Chirkova, Abdulkarim A. Amirov et al.
Journal of Composites Science
Advanced Materials and Mechanics
article

A Model of a “Smart” Thermoresponsive Composite with Convertible Surface Geometry Controlled by the Magnetocaloric Effect

E. K. Murliev, А. П. Каманцев, I. М. Chirkova, Abdulkarim A. Amirov, D. M. Yusupov, Maksim A. Koliushenkov
article en

Abstract

A model of a “smart” composite based on a thermosensitive PNIPAM polymer deposited on a FeRh substrate with a modified periodic microstructure was proposed. The initial parameters of the model were determined from the properties of the actual composite sample and its components. Cooling of the sample using a magnetic field was shown by two independent methods, and at ~37 °C, it was −5.5 °C when a magnetic field of 1.8 T was applied. Based on experimental data, models of traditional and modified PNIPAM/FeRh composites were constructed. Calculations show that surface modification allows for an increase in the activation time for a polymer layer that is 20 µm thick from ~20 ms for a conventional composite to ~60 ms for a modified composite. Modification of the surface in the form of wells can be used to more effectively implement the idea of loading and releasing drugs for potential biomedical applications.

Journal of Composites ScienceVol. 9(3)
National University of Science and Technology (RU), Lomonosov Moscow State University (RU), Hochschule Bielefeld (DE), Institute of Physics. HI Amirkhanova (RU), Kotelnikov Institute of Radioengineering and Electronics of the Russian Academy of Sciences (RU)
Russian Science Foundation
Openalex Percentile: Top 97%
Advanced Materials and Mechanics
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