Visible-light-driven photocatalytic degradation of organic dyes using a TiO2 and waste-based carbon dots nanocomposite

Herein we report a visible-light-active photocatalytic nanocomposite (NC 50:50 ) prepared from carbon dots (CDs) and TiO 2 nanoparticles, which was applied to the photodegradation of organic dyes in water. The CDs incorporated corn stover, a major agricultural waste, and were prepared via hydrothermal treatment. Using a visible-light irradiation source and the dye methylene blue as a representative of the organic dyes class, we observed that a 374 % enhancement of the catalytic performance was achieved by adding CDs relative to bare TiO 2 . This was possible due to increased visible-light absorption and better photonic efficiency. Tests using reactive species scavengers indicated that three active species (superoxide anion, hydroxyl radicals, and electrons) were responsible for the photodegradation process, differing from bare TiO 2 in which only the hydroxyl radical has a relevant role. Photocatalytic degradation was also observed toward Rhodamine B, Orange II and Methyl Orange. Finally, we performed a life cycle assessment (LCA) study to assess and analyse the associated environmental impacts of NC 50:50 compared with other alternatives, which revealed that NC 50:50 is the alternative resulting in the least environmental impacts. In summary, NC 50:50 could, under visible-light irradiation, efficiently remove different organic dyes while incorporating organic waste materials and reducing the impacts associated with their use. We expect that this study provides a base for a more environmentally sustainable design of visible-light-active photocatalysts via waste upcycling. • Visible-light active photocatalysts (NC 50:50 ) were made from TiO 2 and Carbon Dots. • Waste upcycling was achieved by incorporating corn stover in the Carbon Dots. • NC 50:50 presented an improved visible-light absorption and photonic efficiency. • NC 50:50 presented a 374 % enhancement of the catalytic efficiency compared to TiO 2. • The relative environmental impact of NC 50:50 was much lower than those of TiO 2.