Boosting New Electrochemical Reactor Designs to Improve the Performance in H<sub>2</sub>O<sub>2</sub> Production Using Gas Diffusion Electrodes

This work presents a novel electrochemical cell design, developed using 3D printing technology, which enhances turbulence within the cell to promote increased hydrogen peroxide production. This new design is compared to a conventional flow cell that utilizes the same electrodes, membrane, and interelectrode distance, which has demonstrated strong performance in previous studies. Fluid dynamics and H<sub>2</sub>O<sub>2</sub> production are analyzed in both reactors to assess their performance. Additionally, a scale factor of 12.5 is applied to the new concept to evaluate its effectiveness on a larger scale and increase the technology readiness level (TRL). The results demonstrate Faradaic efficiencies of 90% and energy consumption as low as 13 kW h kg<sup>-1</sup>, placing them among the highest reported in the literature. The use of identical materials and operating conditions underscores the critical role of mechanical design in electrochemical cells, suggesting that future research in environmental electrochemical technology should prioritize cell designs tailored to specific target processes.

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Publication Details

Journal
ACS Sustainable Chemistry & Engineering
Published
2025-02-20
DOI
https://doi.org/10.1021/acssuschemeng.4c08826
Citations
11
Primary Topic
Advanced oxidation water treatment
Type
article
Field-Weighted Citation Impact
8.99

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article

Boosting New Electrochemical Reactor Designs to Improve the Performance in H2O2 Production Using Gas Diffusion Electrodes

Marcos R.V. Lanza, Justo Lobato, Taynara Oliveira Silva, Manuel A. Rodrigo et al.
11 citations
ACS Sustainable Chemistry & Engineering
Advanced oxidation water treatment
8.99
article

Boosting New Electrochemical Reactor Designs to Improve the Performance in H2O2 Production Using Gas Diffusion Electrodes

Marcos R.V. Lanza, Justo Lobato, Taynara Oliveira Silva, Manuel A. Rodrigo, Rafael Granados‐Fernández
article en
11 citations

Abstract

This work presents a novel electrochemical cell design, developed using 3D printing technology, which enhances turbulence within the cell to promote increased hydrogen peroxide production. This new design is compared to a conventional flow cell that utilizes the same electrodes, membrane, and interelectrode distance, which has demonstrated strong performance in previous studies. Fluid dynamics and H<sub>2</sub>O<sub>2</sub> production are analyzed in both reactors to assess their performance. Additionally, a scale factor of 12.5 is applied to the new concept to evaluate its effectiveness on a larger scale and increase the technology readiness level (TRL). The results demonstrate Faradaic efficiencies of 90% and energy consumption as low as 13 kW h kg<sup>-1</sup>, placing them among the highest reported in the literature. The use of identical materials and operating conditions underscores the critical role of mechanical design in electrochemical cells, suggesting that future research in environmental electrochemical technology should prioritize cell designs tailored to specific target processes.

ACS Sustainable Chemistry & EngineeringVol. 13(8)
Universidade de São Paulo (BR), University of Castilla-La Mancha (ES)
Fundação de Amparo à Pesquisa do Estado de São Paulo, Conselho Nacional de Desenvolvimento Científico e Tecnológico, Agencia Estatal de Investigación
Affordable and clean energy
Openalex Percentile: Top 2%
Advanced oxidation water treatment
8.99
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Boosting New Electrochemical Reactor Designs to Improve the Performance in H<sub>2</sub>O<sub>2</sub> Production Using Gas Diffusion Electrodes — Marcos R.V. Lanza, Justo Lobato, et al. · ACS Sustainable Chemistry & Engineering (2025) | TGRS Research Map | TGRS