Design of a recyclable Y2O3-g-C3N4 as an auspicious nanosorbent for removing malachite green dye

The recent development of industrial and agricultural technology has led to severe environmental damage, most notably water pollution, which poses a serious threat to water security, considering population increases and a decrease in global drinking water sources. In this direction, a nanostructure (Y 2 O 3 -g-C 3 N 4 ) with a BET surface area of 82.14 m 2 . g −1 was employed for the first time as a novel sorbent to remove malachite green (MG) from the aqueous phase. Besides, the SEM, TEM, and EDX data verified the integration of 14.17 nm Y 2 O 3 nanoparticles into the g-C 3 N 4 nanosheets. The experimental adsorption results confirmed the best fitting to the well-known Langmuir isotherm equation, achieving q max = 1297 mg g 1 of MG uptake, and the kinetic model calculations revealed a single-step mechanism involving a pseudo-second-order chemical reaction with a rate constant of 0.00134 mg./mg. min, which accounted for the chemisorption of MG dye on the Y 2 O 3 -g-C 3 N 4 nanostructure sample. Due to its ease of manufacture and ecologically acceptable procedure, the Y 2 O 3 -g-C 3 N 4 nanostructure was recognized as a desirable and promising candidate for eradicating tainted organic dyes. The newly synthesized Y 2 O 3 -g-C 3 N 4 nanostructure with a high surface area demonstrated a short contact time, outstanding removal capacity, five times recyclability, and multiple dyes elimination nominating it a potentially valuable nanosorbent for the adsorption of dyes from wastewater.

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Journal
Journal of Science Advanced Materials and Devices
Published
2025-02-20
DOI
https://doi.org/10.1016/j.jsamd.2025.100867
Primary Topic
Advanced Photocatalysis Techniques
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article
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article

Design of a recyclable Y2O3-g-C3N4 as an auspicious nanosorbent for removing malachite green dye

Eida S. Al‐Farraj, Hanadi Abdelsalam, Zainab Mufarreh Elqahtani, Osman İsmail et al.
Journal of Science Advanced Materials and Devices
Advanced Photocatalysis Techniques
article

Design of a recyclable Y2O3-g-C3N4 as an auspicious nanosorbent for removing malachite green dye

Eida S. Al‐Farraj, Hanadi Abdelsalam, Zainab Mufarreh Elqahtani, Osman İsmail, A. Modwi, Azizah A. Algreiby, Tahani M. Albogami
article en

Abstract

The recent development of industrial and agricultural technology has led to severe environmental damage, most notably water pollution, which poses a serious threat to water security, considering population increases and a decrease in global drinking water sources. In this direction, a nanostructure (Y 2 O 3 -g-C 3 N 4 ) with a BET surface area of 82.14 m 2 . g −1 was employed for the first time as a novel sorbent to remove malachite green (MG) from the aqueous phase. Besides, the SEM, TEM, and EDX data verified the integration of 14.17 nm Y 2 O 3 nanoparticles into the g-C 3 N 4 nanosheets. The experimental adsorption results confirmed the best fitting to the well-known Langmuir isotherm equation, achieving q max = 1297 mg g 1 of MG uptake, and the kinetic model calculations revealed a single-step mechanism involving a pseudo-second-order chemical reaction with a rate constant of 0.00134 mg./mg. min, which accounted for the chemisorption of MG dye on the Y 2 O 3 -g-C 3 N 4 nanostructure sample. Due to its ease of manufacture and ecologically acceptable procedure, the Y 2 O 3 -g-C 3 N 4 nanostructure was recognized as a desirable and promising candidate for eradicating tainted organic dyes. The newly synthesized Y 2 O 3 -g-C 3 N 4 nanostructure with a high surface area demonstrated a short contact time, outstanding removal capacity, five times recyclability, and multiple dyes elimination nominating it a potentially valuable nanosorbent for the adsorption of dyes from wastewater.

Journal of Science Advanced Materials and DevicesVol. 10(2)
Princess Nourah bint Abdulrahman University (SA), Prince Mohammad bin Fahd University (SA), Qassim University (SA), Taif University (SA), Imam Mohammad ibn Saud Islamic University (SA)
Openalex Percentile: Top 98%
Advanced Photocatalysis Techniques
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