Unlocking New Frontiers: Photo‐Isomerism and Magnetic Properties in Multifunctional Hetero‐Tetra‐Metallic Complexes
Hetero-tetra-metallic complexes, Fe<sub>NO</sub>CuLnCo (Ln=Gd, Tb, Dy), combining magnetic properties and photo-isomerism, were obtained through the rational assembly of the photo-switching nitroprusside anion Fe<sub>NO</sub> with new magnetic Schiff base CuLnCo precursors. Herein, we describe the synthesis and characterisation of these compounds followed by a demonstration of their multifunctional character. Particularly noteworthy is the Fe<sub>NO</sub>CuTbCo complex which is one of the few examples of a photo-isomerisable SMM.
Authors
- Jérémy Forté (ORCID: https://orcid.org/0000-0002-9363-4162)
- Sébastien Pillet (ORCID: https://orcid.org/0000-0003-0530-5244)
- Ingrid Suzana (ORCID: https://orcid.org/0000-0002-5465-681X)
- Valérie Marvaud (ORCID: https://orcid.org/0000-0002-9322-9212)
- Moritz Malischewski (ORCID: https://orcid.org/0000-0002-6756-2951)
- El‐Eulmi Bendeif (ORCID: https://orcid.org/0000-0001-6187-9889)
Institutions
- Centre National de la Recherche Scientifique (FR)
- Sorbonne Université (FR)
- Laboratoire de Cristallographie, Résonance Magnétique et Modélisations (FR)
- Institut Parisien de Chimie Moléculaire (FR)
- Freie Universität Berlin (DE)
- Université de Lorraine (FR)
Publication Details
- Journal
- Chemistry - A European Journal
- Published
- 2025-02-18
- DOI
- https://doi.org/10.1002/chem.202402601
- Citations
- 1
- Primary Topic
- Magnetism in coordination complexes
- Type
- article
- Field-Weighted Citation Impact
- 0.43
Funders
- Deutscher Akademischer Austauschdienst
- Deutsche Forschungsgemeinschaft
- Agence Nationale de la Recherche
- Centre National de la Recherche Scientifique
- Sorbonne Université