Structure, Spectral Characteristics, and Phase Transitions in the Rb3CoCl4NO3 Crystal

Rb3CoCl4NO3 samples applicable for studying spectral characteristics have been obtained for the first time and investigated in the wavelength range λ = 200–800 nm. Transparency windows are found at the UV–visible and visible–IR boundaries. Differential-scanning calorimetry/thermogravimetry analysis revealed that the Rb3CoCl4NO3 crystal is thermally stable, melts without decomposition, and undergoes two reversible phase transitions. The structure of Rb3CoCl4NO3 single crystals was studied by X-ray diffraction in the temperature range of 293–625 K.

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Journal
Crystallography Reports
Published
2024-12-01
DOI
https://doi.org/10.1134/s1063774524602089
Primary Topic
Solid-state spectroscopy and crystallography
Type
article
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article

Structure, Spectral Characteristics, and Phase Transitions in the Rb3CoCl4NO3 Crystal

I. S. Timakov, А. Э. Волошин, Н. И. Сорокина, A. V. Gudymenko et al.
Crystallography Reports
Solid-state spectroscopy and crystallography
article

Structure, Spectral Characteristics, and Phase Transitions in the Rb3CoCl4NO3 Crystal

I. S. Timakov, А. Э. Волошин, Н. И. Сорокина, A. V. Gudymenko, В. А. Коморников, Timofei A. Sorokin, D. S. Matveeva
article en

Abstract

Rb3CoCl4NO3 samples applicable for studying spectral characteristics have been obtained for the first time and investigated in the wavelength range λ = 200–800 nm. Transparency windows are found at the UV–visible and visible–IR boundaries. Differential-scanning calorimetry/thermogravimetry analysis revealed that the Rb3CoCl4NO3 crystal is thermally stable, melts without decomposition, and undergoes two reversible phase transitions. The structure of Rb3CoCl4NO3 single crystals was studied by X-ray diffraction in the temperature range of 293–625 K.

Crystallography ReportsVol. 69(7)
National University of Science and Technology (RU), D. Mendeleyev University of Chemical Technology of Russia (RU), Kurchatov Institute (RU), A.V. Shubnikov Institute of Crystallography (RU)
Openalex Percentile: Top 83%
Solid-state spectroscopy and crystallography
DOISourceOpenAlex
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Structure, Spectral Characteristics, and Phase Transitions in the Rb3CoCl4NO3 Crystal — I. S. Timakov, А. Э. Волошин, et al. · Crystallography Reports (2024) | TGRS Research Map | TGRS