Electrically-Induced Droplet Detachment and Transport on Bionic Honeycomb-Fiber Composite Surfaces
The complex regulation of droplet dynamics, based on the application of external electric fields and micro/nano functional surfaces, has garnered widespread attention in fields such as enhanced oil-water separation, self-cleaning systems, and novel imaging technologies. In this study, a PLE surface (composite biomimetic hydrophobic surface with micron-level honeycomb texture and nanoscale villi) was fabricated. Using a high-speed microscopy system, the detachment and movement of droplets on the biomimetic surface under a direct current electric field were experimentally investigated. By introducing a biomimetic surface correction factor, (ξ), a polarization and force model for droplets on the PLE surface was established. The results indicate that the amount of polarized charge (<i>Q</i>) is positively correlated with the radius (<i>R</i><sup>2</sup>), while the deformation degree (λ) is proportional to the electric field intensity (<i>E</i><sub>c</sub>). Key parameters for droplet detachment were determined, including the electric field threshold (<i>E</i><sub>c</sub> = 83.4 kV/m) and the correction factor (ξ = 0.1066). The relationship among surface electric field intensity <i>E</i><sub>c</sub>, droplet detachment time (<i>T</i><sub>L</sub>), the ratio of droplet height change (<i>H</i><sub>s</sub>) to initial height (<i>H</i><sub>s0</sub>), droplet velocity (<i>V</i><sub>t</sub>), and contact line ratio (<i>L</i>*) was analyzed. It was found that there exists a power-law relationship between <i>E</i><sub>c</sub> and <i>T</i><sub>L</sub>. Moreover, the PLE surface exhibits a more sensitive response to the applied electric field compared to the PI (polyimide) surface.
Authors
- Yunrui Han (ORCID: https://orcid.org/0000-0001-6614-0995)
- Ziming Yan (ORCID: https://orcid.org/0000-0002-5303-4138)
- Yuling Lü (ORCID: https://orcid.org/0000-0002-4065-6149)
- Kai Guo (ORCID: https://orcid.org/0000-0002-5663-610X)
- Xiaoming Luo (ORCID: https://orcid.org/0000-0003-1797-9924)
- Yin Bai
Institutions
- Shandong University (CN)
- China University of Petroleum, Beijing (CN)
- Lanzhou University of Technology (CN)
- Istituto di Scienze Marine del Consiglio Nazionale delle Ricerche (IT)
- China University of Petroleum, East China (CN)
- Shandong University of Science and Technology (CN)
Publication Details
- Journal
- Langmuir
- Published
- 2025-02-15
- DOI
- https://doi.org/10.1021/acs.langmuir.4c05342
- Citations
- 3
- Primary Topic
- Surface Modification and Superhydrophobicity
- Type
- article
- Field-Weighted Citation Impact
- 1.98
Funders
- National Natural Science Foundation of China