Analyzing Efficiency of Perovskite Solar Cells Under High Illumination Intensities by SCAPS Device Simulation

The perovskite solar cell (PSC) is undergoing intense study to meet sustainable energy and environmental demands. However, large-sized solar cells will degrade the power conversion efficiency, thus concentrating light on small-size devices would be a solution. Here, we report the performance of a p-i-n structured device using CH₃NH₃PbI₃ (MAPbI₃) as the active layer with an area of 6 mm². We prove that the power output would be up to 4.2 mW under 10 Suns compared to the 0.9 mW obtained under 1 Sun; however, this results in an actual efficiency drop of the PSC. Further, using a SCAPS device simulation, we found that the intrinsic properties, such as mobility and defect density, of MAPbI₃ has no profound influence on the relationship between light intensity and power conversion efficiency (PCE), but the series resistance is the dominant limiting factor on the performance of the PSC under high illumination intensities. Our work suggests the potential of perovskite in concentrating photovoltaics and makes recommendations for future development.