Study on the reaction kinetics mechanism and properties of RDX/ADN/FKM2602 composite microspheres

This study prepared a class of RDX-based composite microspheres (RAF) containing ADN and FKM2602. The reaction kinetics of RAF composite microspheres were effectively improved by maintaining the system's high energy and safety performance. In the close packing state, when the heating rate is rapid, the thermal stability of RAF composite microspheres is better than that of RDX; the close packing state will reduce the degree of freedom of RDX and ADN reaction but will increase the degree of freedom of RAF composite microsphere reaction. The thermal conductivity of RAF composite microspheres is close to that of RDX. In the ignition experiment, the flame of RAF composite microspheres can be maintained without the external heat source. Regarding safety, the H 50 of RAF composite microspheres was 274.04% higher than that of RDX. The detonation velocity of RAF composite microspheres is slightly higher than that of raw material RDX. Overall, these findings highlight the effectiveness of ADN in enhancing the reaction kinetics of RDX-based composites.

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Publication Details

Journal
Defence Technology
Published
2025-02-12
DOI
https://doi.org/10.1016/j.dt.2025.02.008
Citations
3
Primary Topic
Thermal and Kinetic Analysis
Type
article
Field-Weighted Citation Impact
1.55
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article

Study on the reaction kinetics mechanism and properties of RDX/ADN/FKM2602 composite microspheres

Tongxiang Liang, Yang Zhao, Chao Pan, Zhenhua Liu et al.
3 citations
Defence Technology
Thermal and Kinetic Analysis
1.55
article

Study on the reaction kinetics mechanism and properties of RDX/ADN/FKM2602 composite microspheres

Tongxiang Liang, Yang Zhao, Chao Pan, Zhenhua Liu, Ning Liu, Jingyu Wang, Xiaodong Li, Xiaofeng Shi
article en
3 citations

Abstract

This study prepared a class of RDX-based composite microspheres (RAF) containing ADN and FKM2602. The reaction kinetics of RAF composite microspheres were effectively improved by maintaining the system's high energy and safety performance. In the close packing state, when the heating rate is rapid, the thermal stability of RAF composite microspheres is better than that of RDX; the close packing state will reduce the degree of freedom of RDX and ADN reaction but will increase the degree of freedom of RAF composite microsphere reaction. The thermal conductivity of RAF composite microspheres is close to that of RDX. In the ignition experiment, the flame of RAF composite microspheres can be maintained without the external heat source. Regarding safety, the H 50 of RAF composite microspheres was 274.04% higher than that of RDX. The detonation velocity of RAF composite microspheres is slightly higher than that of raw material RDX. Overall, these findings highlight the effectiveness of ADN in enhancing the reaction kinetics of RDX-based composites.

Defence TechnologyVol. 48
North University of China (CN), Modern Electron (United States) (US)
Openalex Percentile: Top 20%
Thermal and Kinetic Analysis
1.55
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Study on the reaction kinetics mechanism and properties of RDX/ADN/FKM2602 composite microspheres — Tongxiang Liang, Yang Zhao, et al. · Defence Technology (2025) | TGRS Research Map | TGRS