Comparative Study of In Situ TiO2 Generation for the Degradation of “Deiman Navy Blue” Dye

This study presents the development and application of a batch-type photoelectrochemical reactor employing advanced oxidation processes (AOPs) with in situ generated TiO2 particles for the efficient degradation of azo dyes. The reactor uses titanium sheets as electrodes, facilitating the electrochemical generation of TiO2, which acts as a photocatalyst under UV light. This study specifically targets azo dyes frequently encountered in industrial wastewater, focusing on Brilliant Blue, Erythrosine, and Tartrazine, which together form the Navy Blue dye composition. The experimental methodology replicates real-world conditions, ensuring the results are representative of practical scenarios. Key findings demonstrate that the in situ production of TiO2 enables effective heterogeneous photocatalysis, achieving significant dye degradation rates. This research highlights the novelty of combining in situ TiO2 generation with a batch-type reactor, offering advantages in cost-effectiveness, scalability, and environmental impact. Comparative analysis with existing methods underscores the reactor’s potential for industrial applications, particularly in wastewater treatment. Furthermore, this study outlines the mechanistic insights into dye degradation and provides a foundation for optimizing photocatalytic processes to address environmental challenges.