A Novel Electrochemical Platform Based on Cadmium (II) (fluorophenyl)Porphyrin and Gold Nanoparticles Modified Screen‐Printed Electrode Electrode for the Sensitive Detection of Bisphenol A
Bisphenol A (BPA) is categorized as an endocrine‐disrupting substance; it is a risky substance to both environmental and human health, necessitating monitoring. In this present study, a novel electrochemical sensing platform based on Cd metalloporphyrin ([(5,10,15,20‐ tetrakis(p‐flurophenyl) porphyrinato] cadmium (II) [CdTFPP]) and gold nanoparticles (AuNPs) for a rapid and sensitive determination of BPA was designed. To confirm the successful synthesis of CdTFPP, UV/vis, IR, and 1 H NMR were employed. The detection platform CdTFPP/AuNPs/SPCE was prepared using a screen‐printed electrode (SPCE), through the deposition of AuNPs and CdTFPP by drop‐casting. Under optimized measuring conditions, the developed sensor exhibited two linear ranges from 10 −10 to 10 −7 M and 10 −7 to 10 −2 M with a limit of detection of 133 pM. Additionally, the CdTFPP/AuNPs/SPCE/ electrode demonstrated to present an excellent selectivity and reproducibility and to be a promising tool for the development of simple low‐cost water quality monitoring system for BPA detection.
Authors
- Fatma Rejab (ORCID: https://orcid.org/0000-0002-4457-268X)
- Habib Nasri (ORCID: https://orcid.org/0000-0002-7565-8240)
- Hamdi Ben Halima (ORCID: https://orcid.org/0000-0001-8308-1755)
- A. Rouis (ORCID: https://orcid.org/0000-0002-9480-061X)
- Nour Elhouda Dardouri (ORCID: https://orcid.org/0000-0001-7586-1508)
- Mosaab Echabaane (ORCID: https://orcid.org/0000-0001-9230-3815)
- Nicole J. Jaffrezic-Renault (ORCID: https://orcid.org/0000-0003-1354-9273)
Institutions
- Centre National de la Recherche Scientifique (FR)
- University of Monastir (TN)
- Centre de Recherche en Microelectronique et Nanotechnologie
- University of Sousse (TN)
- Université de Franche-Comté (FR)
Publication Details
- Journal
- Electroanalysis
- Published
- 2025-02-01
- DOI
- https://doi.org/10.1002/elan.12017
- Citations
- 4
- Primary Topic
- Conducting polymers and applications
- Type
- article
- Field-Weighted Citation Impact
- 2.43
Funders
- Université Monastir