Synthesis and Structure of Water-Soluble Complexes of Copper Fumarate and Succinate with Monoethanolamine
New water-soluble copper(II) complexes with dicarboxylic acids were obtained by the heterogeneous reaction of copper hydroxy carbonate with succinic or fumaric acid in water at 50°C. The additional introduction of monoethanolamine (MEA) into the complexes ensured high solubility of copper succinate and fumarate. The structures of the complexes [Cu(Suc)·2MEA]·H2O and [Cu(Fum)·2MEA]·H2O were studied by X-ray diffraction (CCDC nos. 2352578 and 2352579, respectively). The compounds were found to have a polymeric structure composed of zigzag chains.
Authors
- Н. М. Лазарев (ORCID: https://orcid.org/0000-0002-3099-2077)
- M. A. Lopatin
- E.V. Baranov (ORCID: https://orcid.org/0000-0002-1923-6879)
- В. В. Семенов (ORCID: https://orcid.org/0000-0002-7216-769X)
- Б. И. Петров
Institutions
- G.A. Razuvaev Institute of Organometallic Chemistry (RU)
Publication Details
- Journal
- Russian Journal of Coordination Chemistry
- Published
- 2024-11-01
- DOI
- https://doi.org/10.1134/s1070328424600785
- Primary Topic
- Crystal structures of chemical compounds
- Type
- article
- Field-Weighted Citation Impact
- 0.00