Activity Coefficients and Partial-Molar Heats of Mixing at Unlimited Dilution of the Components for the Dimethylzinc - Dimethyl Telluride System

Using a semi-empirical model, the vapor-liquid equilibrium is described in the dimethylzinc-dimethyl telluride system: the activity coefficients of the solution components and the partial-molar heats of mixing at infinite dilution are calculated. The primary data for the application of the semi-empirical model were obtained by us from measuring the temperature dependence of the saturated vapor pressure of highly pure samples of dimethylzinc, dimethyl telluride and their solutions.

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Publication Details

Journal
Chemistry & Chemical Technology
Published
2024-12-20
DOI
https://doi.org/10.23939/chcht18.04.458
Primary Topic
Chemical Thermodynamics and Molecular Structure
Type
article
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article

Activity Coefficients and Partial-Molar Heats of Mixing at Unlimited Dilution of the Components for the Dimethylzinc - Dimethyl Telluride System

Valentyn Serheyev, S. I. Gerasymchuk, Ihor Poliuzhyn
Chemistry & Chemical Technology
Chemical Thermodynamics and Molecular Structure
article

Activity Coefficients and Partial-Molar Heats of Mixing at Unlimited Dilution of the Components for the Dimethylzinc - Dimethyl Telluride System

Valentyn Serheyev, S. I. Gerasymchuk, Ihor Poliuzhyn
article en

Abstract

Using a semi-empirical model, the vapor-liquid equilibrium is described in the dimethylzinc-dimethyl telluride system: the activity coefficients of the solution components and the partial-molar heats of mixing at infinite dilution are calculated. The primary data for the application of the semi-empirical model were obtained by us from measuring the temperature dependence of the saturated vapor pressure of highly pure samples of dimethylzinc, dimethyl telluride and their solutions.

Chemistry & Chemical TechnologyVol. 18(4)
Openalex Percentile: Top 81%
Chemical Thermodynamics and Molecular Structure
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