Electrically Tunable Ultraflat Bands and π-Electron Magnetism in Graphene Nanoribbons

Atomically thin crystals hosting flat electronic bands have recently been identified as a rich playground for exploring and engineering strongly correlated phases. Yet, their variety remains limited, primarily to two-dimensional moiré superlattices. Here, we predict the formation of reversible, electrically induced ultraflat bands and π-electron magnetism in one-dimensional chevron graphene nanoribbons. Our <i>ab initio</i> calculations show that the application of a transverse electric field to these nanoribbons generates a pair of isolated, nearly perfectly flat bands with widths of approximately 1 meV around the Fermi level. Upon charge doping, these flat bands undergo a Stoner-like electronic instability, resulting in the spontaneous emergence of local magnetic moments at the edges of the otherwise nonmagnetic nanoribbon, akin to a one-dimensional spin-1/2 chain. Our findings expand the class of carbon-based nanostructures exhibiting flat bands and establish a novel route for inducing correlated electronic phases in chevron graphene nanoribbons.