Modern Approaches to Disposal of Polymers for Household Use

In the present work, we solved the problem of converting low-density polyethylene waste into a powder state as the first stage of involving plastic in the biogeochemical processes of its natural degradation. Acceleration of the fragmentation of polyethylene waste was ensured by adding 2D graphene structures (few-layer graphenes, FLGs), obtained by carbonization of precursors represented by natural materials (glucose, starch, cellulose, lignin, cedar bark, and Sosnowski’s hogweed biomass), to the polymer matrix. It was shown that polyethylene modification with few-layer graphenes leads to a sharp drop in elasticity of the resulting composites compared to the original polyethylene. At the same time, the strength of the composite under deformations acceptable for disposable polymer products remains at the level of the original polymer, which provides the necessary service life of products made from the proposed composites. The FLGs obtained by carbonization of lignin and cedar bark were suggested as optimal modifiers for obtaining polyethylene-based composites such that products thereof can be involved in microbial recycling.

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Publication Details

Journal
Russian Journal of General Chemistry
Published
2024-12-01
DOI
https://doi.org/10.1134/s1070363224130152
Primary Topic
Microplastics and Plastic Pollution
Type
article
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article

Modern Approaches to Disposal of Polymers for Household Use

И. В. Шугалей, А. P. Voznyakovskii, Aleksei Vozniakovskii, A. Yu. Neverovskaya et al.
Russian Journal of General Chemistry
Microplastics and Plastic Pollution
article

Modern Approaches to Disposal of Polymers for Household Use

И. В. Шугалей, А. P. Voznyakovskii, Aleksei Vozniakovskii, A. Yu. Neverovskaya, Ф. Содиков, Д. Рашидов, С. Х. Табаров, Sh. P. Ismatov
article en

Abstract

In the present work, we solved the problem of converting low-density polyethylene waste into a powder state as the first stage of involving plastic in the biogeochemical processes of its natural degradation. Acceleration of the fragmentation of polyethylene waste was ensured by adding 2D graphene structures (few-layer graphenes, FLGs), obtained by carbonization of precursors represented by natural materials (glucose, starch, cellulose, lignin, cedar bark, and Sosnowski’s hogweed biomass), to the polymer matrix. It was shown that polyethylene modification with few-layer graphenes leads to a sharp drop in elasticity of the resulting composites compared to the original polyethylene. At the same time, the strength of the composite under deformations acceptable for disposable polymer products remains at the level of the original polymer, which provides the necessary service life of products made from the proposed composites. The FLGs obtained by carbonization of lignin and cedar bark were suggested as optimal modifiers for obtaining polyethylene-based composites such that products thereof can be involved in microbial recycling.

Russian Journal of General ChemistryVol. 94(13)
Russian Academy of Sciences (RU), Tajik National University (TJ), Physico-Technical Institute (RU), Synthetic Rubber Research Institute named after S. V. Lebedeva (RU), St. Petersburg State Technological Institute (RU)
Zero hunger
Openalex Percentile: Top 84%
Microplastics and Plastic Pollution
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Modern Approaches to Disposal of Polymers for Household Use — И. В. Шугалей, А. P. Voznyakovskii, et al. · Russian Journal of General Chemistry (2024) | TGRS Research Map | TGRS