Characterization and Source Apportionment Analysis of PM2.5 and Ozone Pollution over Fenwei Plain, China: Insights from PM2.5 Component and VOC Observations

PM_2.5 and volatile organic compounds (VOCs) have been identified as the primary air pollutants affecting the Fenwei Plain (FWP), necessitating urgent measures to improve its air quality. To gain a deeper understanding of the formation mechanisms of these pollutants, this study employed various methods such as HYSPLIT, PCT, and PMF for analysis. Our results indicate that the FWP is primarily impacted by PM_2.5 from the southern Shaanxi air mass and the northwestern air mass during winter. In contrast, during summer, it is mainly influenced by O₃ originating from the southern air mass. Specifically, high-pressure fronts are the dominant weather pattern affecting PM_2.5 pollution in the FWP, while high-pressure backs predominately O₃ pollution. Regarding the sources of PM_2.5, secondary nitrates, vehicle exhausts, and secondary sulfates are major contributors. As for volatile organic compounds, liquefied petroleum gas sources, vehicle exhausts, solvent usage, and industrial emissions are the primary sources. This study holds crucial scientific significance in enhancing the regional joint prevention and control mechanism for PM_2.5 and O₃ pollution, and it provides scientific support for formulating effective strategies for air pollution prevention and control.