Fabrication of a Phosphor‐in‐Silica Glass Spectral Converter via Injection Molding for Stable and High‐Power Broadband LEDs
Abstract The encapsulation of phosphor particles into a silica glass (PiSG) matrix leads to the formation of an efficient and chemically durable spectral converter, which is a promising candidate for the fabrication of stable and high‐power phosphor‐converted white light‐emitting‐diodes (pc‐wLEDs). Here, high‐throughput fabrication of transparent PiSG spectral converters based on Y 3 Al 5 O 12 :Ce 3+ , Mg 2 Al 4 Si 5 O 18 :Eu 2+ , and Y 3 Al 5 O 12 :Cr 3+ is demonstrated via injection molding followed by pressureless sintering. The as‐fabricated PiSG exhibits broadband emission covering the visible and near‐infrared (vis‐NIR) spectral regions (i.e., 500–900 nm) with a high‐luminescence efficiency (> 85%) and high‐chemical and thermal stabilities, retaining more than 90% of its emission intensity at 200 °C. Consequently, high‐power pc‐vis‐NIR‐LEDs (10 W) are manufactured using the injection molded PiSG spectral converters, which showed excellent luminescence performance (i.e., luminous efficiency (LE) = 115 Im W −1 , correlated‐color‐temperature (CCT) = 4531 K, and color‐rendering‐index (R a ) = 90.1 at 50 mA and input power of 0.45 W). This work enables the fabrication of stable and high‐power broadband LEDs with a low cost and outstanding optical properties, making the as‐fabricated pc‐vis‐NIR‐LEDs based on PiSG spectral‐converter a favorable device for lighting and bioimaging applications.
Authors
- Moushira. A. Mohamed (ORCID: https://orcid.org/0000-0003-1092-7558)
- M.A. Ali (ORCID: https://orcid.org/0000-0002-8371-4599)
- Xiaofeng Liu (ORCID: https://orcid.org/0000-0003-4576-9094)
- Jianrong Qiu (ORCID: https://orcid.org/0000-0002-2733-0224)
- Shaorun Guo
- Shengzhi Sun (ORCID: https://orcid.org/0000-0001-9635-7853)
Institutions
- Ningbo University (CN)
- State Key Laboratory of Modern Optical Instruments (CN)
- Zhejiang University (CN)
Publication Details
- Journal
- Advanced Optical Materials
- Published
- 2025-02-06
- DOI
- https://doi.org/10.1002/adom.202403434
- Citations
- 7
- Primary Topic
- Luminescence Properties of Advanced Materials
- Type
- article
- Field-Weighted Citation Impact
- 3.62
Funders
- National Natural Science Foundation of China
- National Key Research and Development Program of China