Cp2ZrCl2-Catalyzed 2-Aluminoethylalumination of Aminomethyl Allenes with Triethylaluminum
It was shown for the first time that the Cp2ZrCl2-catalyzed reaction of dialkylaminomethyl allenes (N,N-dialkylbuta-2,3-dien-1-amines) with triethylaluminum results in regio- and stereoselective formation of (Z)-N,N-dialkylhex-2-en-1-amines. A probable reaction mechanism has been proposed.
Authors
- И. Р. Рамазанов (ORCID: https://orcid.org/0000-0002-3846-6581)
- Rita N. Kadikova (ORCID: https://orcid.org/0000-0002-4636-1739)
- T. P. Zosim (ORCID: https://orcid.org/0000-0003-2658-0261)
Institutions
- Ufa Institute of Chemistry (RU)
Publication Details
- Journal
- Russian Journal of Organic Chemistry
- Published
- 2024-12-01
- DOI
- https://doi.org/10.1134/s1070428024120261
- Primary Topic
- Catalytic Cross-Coupling Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00