Methyl 5-[Di(1H-pyrrol-2-yl)methyl]-3,4-dimethoxythiophene-2-carboxylate in Approaches to New Thienopyrroles

Selective reduction–oxidation of dimethyl 3,4-dimethoxythiophene-2,5-dicarboxylate gave methyl 5-formyl-3,4-dimethoxythiophene-2-carboxylate and then methyl 5-[di(1H-pyrrol-2-yl)methyl]-3,4-dimethoxy­thiophene-2-carboxylate, and the latter was used to obtain the corresponding BODIPY derivative.

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Publication Details

Journal
Russian Journal of Organic Chemistry
Published
2024-12-01
DOI
https://doi.org/10.1134/s1070428024120273
Primary Topic
Porphyrin and Phthalocyanine Chemistry
Type
article
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article

Methyl 5-[Di(1H-pyrrol-2-yl)methyl]-3,4-dimethoxythiophene-2-carboxylate in Approaches to New Thienopyrroles

Ф. А. Гималова, Z. F. Nuriakhmetova, S. A. Torosyan, M. S. Miftakhov
Russian Journal of Organic Chemistry
Porphyrin and Phthalocyanine Chemistry
article

Methyl 5-[Di(1H-pyrrol-2-yl)methyl]-3,4-dimethoxythiophene-2-carboxylate in Approaches to New Thienopyrroles

Ф. А. Гималова, Z. F. Nuriakhmetova, S. A. Torosyan, M. S. Miftakhov
article en

Abstract

Selective reduction–oxidation of dimethyl 3,4-dimethoxythiophene-2,5-dicarboxylate gave methyl 5-formyl-3,4-dimethoxythiophene-2-carboxylate and then methyl 5-[di(1H-pyrrol-2-yl)methyl]-3,4-dimethoxy­thiophene-2-carboxylate, and the latter was used to obtain the corresponding BODIPY derivative.

Russian Journal of Organic ChemistryVol. 60(12)
Ufa Institute of Chemistry (RU)
Openalex Percentile: Top 83%
Porphyrin and Phthalocyanine Chemistry
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