mer-[InCl3(C5D5N)3]2·C5D5N: A New d5-pyridine Derivative of Indium(III) Chloride Complex
In this study, we report the crystal structure of a meridional octahedral pyridine-indium(III) chloride adduct, mer-trichlorotris(d5-pyridine)indium(III)·0.5(d5-pyridine), InCl3(C5D5N)3·0.5(C5D5N), which exhibits an unreported molecule-to-solvent ratio compared to other substituted and unsubstituted pyridine-indium(III) chloride adducts described in earlier literature. The bonding characteristics of this d5-pyridine complex are compared to analogous complexes that have already been reported. Furthermore, the role of this metal complex in indium insertion into corrole ligands is discussed.
Authors
- Anssi Peuronen (ORCID: https://orcid.org/0000-0002-2504-8196)
- Anastassios C. Papageorgiou (ORCID: https://orcid.org/0000-0002-7980-1120)
- Günther Knör (ORCID: https://orcid.org/0000-0002-2259-6496)
- Ali Tuna (ORCID: https://orcid.org/0000-0003-2801-5995)
- Pekka Peljo (ORCID: https://orcid.org/0000-0002-1229-2261)
Institutions
- University of Turku (FI)
Publication Details
- Journal
- Journal of the Turkish Chemical Society Section A Chemistry
- Published
- 2025-02-05
- DOI
- https://doi.org/10.18596/jotcsa.1590991
- Primary Topic
- Inorganic Fluorides and Related Compounds
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Turun Yliopisto
- Universität Zürich
- Biocenter Finland
- Division of Materials Research