Techno-economic analysis of two novel direct air capture-to-urea concepts based on process intensification

Direct Air Capture (DAC) technologies are anticipated to achieve megaton-scale by 2030 and gigaton-scale by 2050. However, current capture costs and pace of development cast doubt on DAC's readiness to contribute to the environmental goals in the 2030s. This study introduces an innovative framework to reduce capture costs and facilitate the widespread deployment of DAC technologies. First, an extensive review of the current state of DAC deployment is conducted, followed by an analysis of the DAC market outlook. Secondly, the methodology involves the techno-economic assessment of our case study, the integration of absorption-based DAC systems with the urea manufacturing process (DAC-to-urea). This leads to the formulation of two First-of-a-kind (FOAK) DAC-urea designs based on process intensification. The initial focus is to demonstrate the technical and economic feasibility of the proposed concepts. FOAK costs are projected into the future by outlining distinct deployment scenarios using the learning rates principle. Estimates from the optimistic deployment case indicate that low renewable electricity prices and ambitious learning rates lead to competitive DAC-based urea prices (611–726 $/t urea), while achieving promising capture costs (154–263 $/tCO₂). In that context, renewable ammonia generation acts as the primary bottleneck for sustainable urea production employing air-captured CO₂. This outcome strengthens DAC-CO₂ role as a chemical feedstock for high-demand commodities in future sustainable economies. However, results derived from the delayed deployment scenarios (280–560$/tCO 2 ) align with innovative cost assessment approaches from the literature. Findings highlight the dependency of DAC cost predictions on elevated learning rates and immense increases in capacity. • DAC progress raises concerns about achieving megaton scale by 2030, while philanthropic purchases dominate the DAC market. • This work suggests two new DAC-to-urea concepts to boost DAC-CO₂ market demand and technology scaling. • A techno-economic analysis is carried out to assess the technical and economic viability of novel concepts. • Different DAC deployment scenarios are defined to examine technological learning and cost of energy impact on capture costs. • The cost reduction of DAC-to-urea depends on low-cost renewables, high learning rates, and substantial capacity increases.