Bridging Freidlin-Wentzell large deviations theory and stochastic thermodynamics

For overdamped Langevin systems subjected to weak thermal noise and nonconservative forces, we establish a connection between Freidlin-Wentzell large deviations theory and stochastic thermodynamics. First, we derive a series expansion of the quasipotential around the detailed-balance solution, that is, the system's free energy, and identify the conditions for the linear response regime to hold, even far from equilibrium. Second, we prove that the escape rate from dissipative fixed points of the macroscopic dynamics is bounded by the entropy production of trajectories that relax into and escape from the attractors. These results provide the foundation to study the nonequilibrium thermodynamics of dissipative metastable states.

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Publication Details

Journal
Physical review. E
Published
2025-02-04
DOI
https://doi.org/10.1103/physreve.111.024106
Citations
2
Primary Topic
Advanced Thermodynamics and Statistical Mechanics
Type
article
Field-Weighted Citation Impact
2.65

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article

Bridging Freidlin-Wentzell large deviations theory and stochastic thermodynamics

Nahuel Freitas, Gianmaria Falasco, Massimiliano Esposito, Davide Santolin
2 citations
Physical review. E
Advanced Thermodynamics and Statistical Mechanics
2.65
article

Bridging Freidlin-Wentzell large deviations theory and stochastic thermodynamics

Nahuel Freitas, Gianmaria Falasco, Massimiliano Esposito, Davide Santolin
article en
2 citations

Abstract

For overdamped Langevin systems subjected to weak thermal noise and nonconservative forces, we establish a connection between Freidlin-Wentzell large deviations theory and stochastic thermodynamics. First, we derive a series expansion of the quasipotential around the detailed-balance solution, that is, the system's free energy, and identify the conditions for the linear response regime to hold, even far from equilibrium. Second, we prove that the escape rate from dissipative fixed points of the macroscopic dynamics is bounded by the entropy production of trajectories that relax into and escape from the attractors. These results provide the foundation to study the nonequilibrium thermodynamics of dissipative metastable states.

Physical review. EVol. 111(2)
University of Padua (IT), University of Luxembourg (LU), Universidad Bicentenaria de Aragua (VE)
European Commission, Fonds De La Recherche Scientifique - FNRS, Università degli Studi di Padova, Department of Forestry and Natural Resources, Purdue University
Openalex Percentile: Top 12%
Advanced Thermodynamics and Statistical Mechanics
2.65
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