To suppress tin whisker growth by using (100)-oriented copper

Effect of Cu crystallographic orientations on the Sn whisker growth is investigated in this study. Three types of Cu under-layer (randomly, <111>, <100>-oriented) were prepared for electroplating of pure Sn. After 672 h of room temperature (RT) storage, a lot of whiskers were found on the Sn surface electroplated on the randomly-oriented Cu, whereas very few whiskers can be seen on those electroplated on the <111>− or the <100>-oriented Cu. It is also found that the behavior of intermetallic compound (IMC) growth at the Sn–Cu interface is quite different between the randomly- and specifically-oriented Cu films, which leads to divergent phenomena of Sn whisker growth. Furthermore, after 7944 h of RT storage, both the <111>− and the <100>-oriented Cu films are proven to be effective on preventing Sn whisker growth. Orientation analysis indicated the Sn grains on the <111>− and the <100>-oriented Cu possesses <110> preferred orientation, which may slow down the formation of the Cu–Sn IMCs.

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Publication Details

Journal
Journal of Materials Research and Technology
Published
2025-02-04
DOI
https://doi.org/10.1016/j.jmrt.2025.02.021
Citations
4
Primary Topic
Electronic Packaging and Soldering Technologies
Type
article
Field-Weighted Citation Impact
2.92
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article

To suppress tin whisker growth by using (100)-oriented copper

K. N. Tu, Chih Chen, Jialing Lu, Christine Hu et al.
4 citations
Journal of Materials Research and Technology
Electronic Packaging and Soldering Technologies
2.92
article

To suppress tin whisker growth by using (100)-oriented copper

K. N. Tu, Chih Chen, Jialing Lu, Christine Hu, Han-wen Lin
article en
4 citations

Abstract

Effect of Cu crystallographic orientations on the Sn whisker growth is investigated in this study. Three types of Cu under-layer (randomly, <111>, <100>-oriented) were prepared for electroplating of pure Sn. After 672 h of room temperature (RT) storage, a lot of whiskers were found on the Sn surface electroplated on the randomly-oriented Cu, whereas very few whiskers can be seen on those electroplated on the <111>− or the <100>-oriented Cu. It is also found that the behavior of intermetallic compound (IMC) growth at the Sn–Cu interface is quite different between the randomly- and specifically-oriented Cu films, which leads to divergent phenomena of Sn whisker growth. Furthermore, after 7944 h of RT storage, both the <111>− and the <100>-oriented Cu films are proven to be effective on preventing Sn whisker growth. Orientation analysis indicated the Sn grains on the <111>− and the <100>-oriented Cu possesses <110> preferred orientation, which may slow down the formation of the Cu–Sn IMCs.

Journal of Materials Research and TechnologyVol. 35
National Yang Ming Chiao Tung University (TW), City University of Hong Kong (HK)
Openalex Percentile: Top 10%
Electronic Packaging and Soldering Technologies
2.92
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