Visible-Light-Induced Phosphorothioation of Alkenyl Sulfonium Salts with S<sub>8</sub> and <i>H</i>-Phosphonates
An efficient and practical method for synthesizing vinyl phosphorothioates has been demonstrated through a visible-light-induced three-component reaction of alkenyl sulfonium salts, S<sub>8</sub>, and <i>H</i>-phosphonates. This method facilitates the synthesis of a diverse range of vinyl phosphorothioates with a wide substrate scope and functional group tolerance. Preliminary mechanistic studies suggest that the reaction involves a phosphorothioate radical-triggered process.
Authors
- Li Tang (ORCID: https://orcid.org/0000-0003-4689-361X)
- Long‐Yong Xie (ORCID: https://orcid.org/0000-0002-8932-7282)
- Ni-Dan Meng
- Shanshan Tang (ORCID: https://orcid.org/0000-0002-7212-0402)
- Lin Chen (ORCID: https://orcid.org/0000-0002-6045-4149)
- Li‐Hua Yang (ORCID: https://orcid.org/0000-0001-7106-3015)
Institutions
- Hunan University of Science and Engineering (CN)
Publication Details
- Journal
- The Journal of Organic Chemistry
- Published
- 2025-02-04
- DOI
- https://doi.org/10.1021/acs.joc.4c02642
- Citations
- 11
- Primary Topic
- Sulfur-Based Synthesis Techniques
- Type
- article
- Field-Weighted Citation Impact
- 10.30