Pd nanoparticles-functionalized In2O3 based gas sensor for highly selective detection of toluene

Given the threat posed by toluene to human health and environmental safety, real-time and efficient detection of toluene assumes paramount importance. However, the low chemical reactivity and structural similarity of benzene, toluene, and xylene (BTX) gases impede the attainment of highly selective toluene detection. Herein, palladium-loaded indium oxide nanospheres were successfully synthesized through a combination of solvothermal and post-reduction methods. And the sensor based on 0.75 wt% Pd-In₂O₃ exhibits the response to the concentration of 100 ppm toluene (R_a/R_g = 21) that is approximately four times better compared to pure indium oxide (R_a/R_g = 4) at their respective optimum operating temperatures. Moreover, this sensor exhibited enhanced sensing performance towards toluene, including a low operating temperature of 160 °C, exceptional selectivity, and good stability. Furthermore, an investigation into the sensing mechanism of toluene by the Pd-In₂O₃-based sensor was conducted. The chemical and electron sensitization effects of palladium result in the more chemisorbed oxygen of the sensing material, which improves the toluene sensing performance by enhancing the reaction with more toluene molecules. Additionally, the moderate catalytic activation of toluene by palladium plays a crucial role in improving the selectivity. Overall, this work provides a basis for the rational design of metal oxide semiconductor sensors with catalytic properties for the highly selective detection of toluene.