Migration and Transformation of Nitrogen in Clay-Rich Soil Under Shallow Groundwater Depth: In Situ Experiment and Numerical Simulation

Excessive use of nitrogen fertilizer in agricultural activities can easily induce nitrogen pollution in groundwater, which may deteriorate groundwater quality. Generally, nitrogen fertilizer passes through the unsaturated zone to groundwater. Therefore, it is of great significance to investigate the migration and transformation of nitrogen pollutants in unsaturated zones for the prevention and control of groundwater nitrogen pollution. Clay-rich soil is often considered a barrier layer to prevent pollutant leakage because of its lower relative permeability, while its prevention capacity is seldom reported under shallow groundwater table conditions. Motivated by this, an in situ experiment and numerical simulation were conducted to investigate the migration and transformation of nitrogen fertilizer in a clay-unsaturated zone with a shallow groundwater table. Systematic measurements and numerical simulation results revealed that nitrogen can pollute groundwater via the infiltration through clay-rich soil in the in situ experiment site. This finding clarified that the difference in hydraulic head under the shallow groundwater table, rather than soil permeability, is the dominant factor in controlling the downward migration of nitrogen pollutants in the clay-unsaturated zone. More importantly, the nitrogen migration is convection dominant during precipitation in this experiment, indicating nitrogen polluted groundwater much faster in humid climate areas. These findings suggest that nitrogen contaminates groundwater easily under shallow groundwater tables in humid climate areas, even with clay-rich soil texture.